海洋二萜异腈（-）-卡里希诺醇Y和二萜异硫氰酸酯（-）-10-表-卡里希诺醇I的合成。

Synthesis of marine diterpene isocyanide (-)-kalihinol Y and diterpene isothiocyanate (-)-10-epi-kalihinol I.

作者信息

Miyaoka Hiroaki, Abe Yasunori, Kawashima Etsuko

机构信息

School of Pharmacy, Tokyo University of Pharmacy and Life Sciences, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan.

出版信息

Chem Pharm Bull (Tokyo). 2012;60(9):1224-6. doi: 10.1248/cpb.c12-00485.

DOI:10.1248/cpb.c12-00485

PMID:22976335

Abstract

The authors described the first synthesis of diterpene isocyanide (-)-kalihinol Y and diterpene isothiocyanate (-)-10-epi-kalihinol I from synthetic intermediates of kalihinol A. The absolute structures of these compounds were confirmed by these syntheses.

摘要

作者描述了从卡里希醇A的合成中间体首次合成二萜异腈（-）-卡里希醇Y和二萜异硫氰酸酯（-）-10-表-卡里希醇I。这些化合物的绝对结构通过这些合成得以确认。