School of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK.
Nat Nanotechnol. 2013 Feb;8(2):100-3. doi: 10.1038/nnano.2012.224. Epub 2012 Dec 23.
The celebrated electronic properties of graphene have opened the way for materials just one atom thick to be used in the post-silicon electronic era. An important milestone was the creation of heterostructures based on graphene and other two-dimensional crystals, which can be assembled into three-dimensional stacks with atomic layer precision. Such layered structures have already demonstrated a range of fascinating physical phenomena, and have also been used in demonstrating a prototype field-effect tunnelling transistor, which is regarded to be a candidate for post-CMOS (complementary metal-oxide semiconductor) technology. The range of possible materials that could be incorporated into such stacks is very large. Indeed, there are many other materials with layers linked by weak van der Waals forces that can be exfoliated and combined together to create novel highly tailored heterostructures. Here, we describe a new generation of field-effect vertical tunnelling transistors where two-dimensional tungsten disulphide serves as an atomically thin barrier between two layers of either mechanically exfoliated or chemical vapour deposition-grown graphene. The combination of tunnelling (under the barrier) and thermionic (over the barrier) transport allows for unprecedented current modulation exceeding 1 × 10(6) at room temperature and very high ON current. These devices can also operate on transparent and flexible substrates.
石墨烯的著名电子特性为后硅时代的电子材料开辟了道路,这些材料只有一个原子厚。一个重要的里程碑是基于石墨烯和其他二维晶体的异质结构的创建,这些异质结构可以以原子层精度组装成三维堆叠。这种分层结构已经展示了一系列迷人的物理现象,并且还被用于展示原型场效应隧穿晶体管,该晶体管被认为是后 CMOS(互补金属氧化物半导体)技术的候选者。可以纳入这种堆叠的可能材料的范围非常大。事实上,有许多其他具有弱范德华力连接的层状材料可以被剥离并组合在一起,以创建新的高度定制的异质结构。在这里,我们描述了新一代场效应垂直隧穿晶体管,其中二维二硫化钨作为两个原子层之间的原子薄势垒,这两个原子层由机械剥落或化学气相沉积生长的石墨烯组成。隧穿(在势垒下)和热电子(在势垒上)传输的组合允许在室温下超过 1×10^6 的前所未有的电流调制,并且具有非常高的导通电流。这些器件还可以在透明和柔性衬底上运行。