高效可见光诱导的有氧氧化 C-C、C-P 偶联反应，由金（III）配合物催化的 C-H 键断裂。
Highly efficient visible-light-induced aerobic oxidative C-C, C-P coupling from C-H bonds catalyzed by a gold(III)-complex.
机构信息
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People's Republic of China.
出版信息
Org Biomol Chem. 2013 Feb 13;11(10):1606-9. doi: 10.1039/c3ob27400d.
PMID:23364576
Abstract
A novel and highly efficient gold(III)-complex catalyzed aerobic oxidative α-C-H functionalization of amines has been developed. The tertiary amines can be directly coupled with various nucleophiles using air as a sustainable oxidant.
摘要
一种新型、高效的金(III)配合物催化的胺类化合物的有氧氧化α-C-H 官能团化反应已经被开发出来。该反应可以使用空气作为可持续氧化剂，将叔胺与各种亲核试剂直接偶联。
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