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通过量子限域来调节剥离的 InSe 纳米片的带隙。

Tuning the bandgap of exfoliated InSe nanosheets by quantum confinement.

机构信息

School of Physics and AstronomyThe University of Nottingham, Nottingham, NG7 2RD, UK.

出版信息

Adv Mater. 2013 Oct 25;25(40):5714-8. doi: 10.1002/adma.201302616. Epub 2013 Aug 21.

DOI:10.1002/adma.201302616
PMID:23966225
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4065344/
Abstract

Strong quantization effects and tuneable near-infrared photoluminescence emission are reported in mechanically exfoliated crystals of γ-rhombohedral semiconducting InSe. The optical properties of InSe nanosheets differ qualitatively from those reported recently for exfoliated transition metal dichalcogenides and indicate a crossover from a direct to an indirect band gap semiconductor when the InSe flake thickness is reduced to a few nanometers.

摘要

本文报道了机械剥离的γ-菱形半导体 InSe 晶体中存在的强量子限制效应和可调谐的近红外光致发光发射。InSe 纳米片的光学性质与最近报道的剥离过渡金属二卤化物的性质明显不同,表明当 InSe 薄片厚度减小到几纳米时,半导体从直接带隙转变为间接带隙。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a24/4065344/bf1d72b0643a/adma0025-5714-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a24/4065344/73e4d95abcc9/adma0025-5714-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a24/4065344/69ac26eddbb0/adma0025-5714-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a24/4065344/ec84073028eb/adma0025-5714-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a24/4065344/bf1d72b0643a/adma0025-5714-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a24/4065344/73e4d95abcc9/adma0025-5714-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a24/4065344/69ac26eddbb0/adma0025-5714-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a24/4065344/ec84073028eb/adma0025-5714-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a24/4065344/bf1d72b0643a/adma0025-5714-f4.jpg

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