School of Engineering and Applied Sciences, Harvard University , 33 Oxford Street, Cambridge, Massachusetts 02138, United States.
Nano Lett. 2014 Feb 12;14(2):524-31. doi: 10.1021/nl403552q. Epub 2014 Jan 27.
This paper describes the fabrication of functional optical devices by sectioning quantum-dot-in-nanowires systems with predefined lengths and orientations. This fabrication process requires only two steps, embedding the nanowires in epoxy and using an ultramicrotome to section them across their axis ("nanoskiving"). This work demonstrates the combination of the following four capabilities: (i) the control of the length of the nanowire sections at the nanometer scale; (ii) the ability to process the nanowires after cutting using wet etching; (iii) the possibility of modifying the geometry of the wire by varying the sectioning angle; and (iv) the generation of as many as 120 consecutive slabs bearing nanowires that have uniform size and approximately reproducible lateral patterns and that can subsequently be transferred to different substrates. The quantum dots inside the nanowires are functional and of a high optical quality after the sectioning process and exhibit photoluminescent emission with wavelengths in the range of 650-710 nm.
本文描述了通过将具有预定义长度和取向的量子点-纳米线系统分段来制造功能光学器件。这种制造工艺只需要两个步骤,即将纳米线嵌入环氧树脂中,并使用超微切片机沿其轴将它们切成薄片(“纳米切割”)。这项工作展示了以下四种能力的结合:(i)在纳米尺度上控制纳米线段的长度;(ii)在切割后使用湿蚀刻处理纳米线的能力;(iii)通过改变分段角度改变线材几何形状的可能性;以及(iv)能够生成多达 120 个连续的承载具有均匀尺寸和可重复的近似横向图案的纳米线的薄片,并且可以随后将它们转移到不同的衬底上。纳米线内部的量子点在分段过程后具有功能性和高光学质量,并表现出波长在 650-710nm 范围内的光致发光发射。