通过铑（III）催化的吡啶甲酰胺的级联氧化烯基化/环化反应合成亚烷基吡咯并[3,4 - b]吡啶 - 7 - 酮衍生物
Synthesis of alkylidene pyrrolo[3,4-b]pyridin-7-one derivatives via Rh(III)-catalyzed cascade oxidative alkenylation/annulation of picolinamides.
作者信息
Martínez Ángel Manu, Rodríguez Nuria, Gómez Arrayás Ramón, Carretero Juan C
机构信息
Departamento de Química Orgánica, Universidad Autónoma de Madrid, Cantoblanco, 28049 Madrid, Spain.
出版信息
Chem Commun (Camb). 2014 Jun 11;50(46):6105-7. doi: 10.1039/c4cc02322f.
PMID:24769892
Abstract
A practical Rh(III)-catalyzed cascade olefination/annulation of picolinamides leading to pyrrolo[3,4-b]pyridines has been developed. The reaction shows wide scope, complete regiocontrol and excellent stereoselectivity.
摘要
已开发出一种实用的铑（III）催化的吡啶甲酰胺的级联烯烃化/环化反应，可生成吡咯并[3,4 - b]吡啶。该反应具有广泛的底物范围、完全的区域选择性和出色的立体选择性。
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