McCaffrey V P, Zellner N E B, Waun C M, Bennett E R, Earl E K
Department of Chemistry, Albion College, Albion, MI, 49224, USA,
Orig Life Evol Biosph. 2014 Feb;44(1):29-42. doi: 10.1007/s11084-014-9358-5. Epub 2014 Jun 17.
Sugars of extraterrestrial origin have been observed in the interstellar medium (ISM), in at least one comet spectrum, and in several carbonaceous chondritic meteorites that have been recovered from the surface of the Earth. The origins of these sugars within the meteorites have been debated. To explore the possibility that sugars could be generated during shock events, this paper reports on the results of the first laboratory impact experiments wherein glycolaldehyde, found in the ISM, as well as glycolaldehyde mixed with montmorillonite clay, have been subjected to reverberated shocks from ~5 to >25 GPa. New biologically relevant molecules, including threose, erythrose and ethylene glycol, were identified in the resulting samples. These results show that sugar molecules can not only survive but also become more complex during impact delivery to planetary bodies.
在星际介质(ISM)、至少一个彗星光谱以及从地球表面回收的几块碳质球粒陨石中都观测到了外星来源的糖类。这些陨石中糖类的起源一直存在争议。为了探究糖类是否可能在撞击事件中产生,本文报告了首次实验室撞击实验的结果,其中,在ISM中发现的乙醇醛以及与蒙脱石粘土混合的乙醇醛,都受到了约5至>25吉帕的回响冲击。在所得样品中鉴定出了新的具有生物学相关性的分子,包括苏糖、赤藓糖和乙二醇。这些结果表明,糖类分子不仅能够存活,而且在撞击传递到行星体的过程中还会变得更加复杂。