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控制尺寸的 CH3NH3PbI3 长方体的生长用于高效钙钛矿太阳能电池。

Growth of CH3NH3PbI3 cuboids with controlled size for high-efficiency perovskite solar cells.

机构信息

School of Chemical Engineering and Department of Energy Science, Sungkyunkwan University, Suwon 440-746, Korea.

1] Laboratory for Photonics and Interfaces, Institute of Chemical Sciences and Engineering, School of Basic Sciences, Ecole Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland [2] Max-Planck-Institute for Solid-State Research, Heisenbergstrasse 1, 70569 Stuttgart, Germany.

出版信息

Nat Nanotechnol. 2014 Nov;9(11):927-32. doi: 10.1038/nnano.2014.181. Epub 2014 Aug 31.

Abstract

Perovskite solar cells with submicrometre-thick CH(3)NH(3)PbI(3) or CH(3)NH(3)PbI(3-x)Cl(x) active layers show a power conversion efficiency as high as 15%. However, compared to the best-performing device, the average efficiency was as low as 12%, with a large standard deviation (s.d.). Here, we report perovskite solar cells with an average efficiency exceeding 16% and best efficiency of 17%. This was enabled by the growth of CH(3)NH(3)PbI(3) cuboids with a controlled size via a two-step spin-coating procedure. Spin-coating of a solution of CH(3)NH(3)I with different concentrations follows the spin-coating of PbI(2), and the cuboid size of CH(3)NH(3)PbI(3) is found to strongly depend on the concentration of CH(3)NH(3)I. Light-harvesting efficiency and charge-carrier extraction are significantly affected by the cuboid size. Under simulated one-sun illumination, average efficiencies of 16.4% (s.d. ± 0.35), 16.3% (s.d. ± 0.44) and 13.5% (s.d. ± 0.34) are obtained from solutions of CH(3)NH(3)I with concentrations of 0.038 M, 0.050 M and 0.063 M, respectively. By controlling the size of the cuboids of CH(3)NH(3)PbI(3) during their growth, we achieved the best efficiency of 17.01% with a photocurrent density of 21.64 mA cm(-2), open-circuit photovoltage of 1.056 V and fill factor of 0.741.

摘要

具有亚微米厚 CH(3)NH(3)PbI(3) 或 CH(3)NH(3)PbI(3-x)Cl(x) 活性层的钙钛矿太阳能电池的功率转换效率高达 15%。然而,与性能最佳的器件相比,平均效率低至 12%,标准偏差较大(s.d.)。在这里,我们报告了平均效率超过 16%且最佳效率为 17%的钙钛矿太阳能电池。这是通过两步旋涂工艺控制 CH(3)NH(3)PbI(3) 长方体的生长来实现的。CH(3)NH(3)I 不同浓度溶液的旋涂紧随 PbI(2) 的旋涂之后,并且 CH(3)NH(3)PbI(3) 的长方体尺寸强烈依赖于 CH(3)NH(3)I 的浓度。光捕获效率和载流子提取受长方体尺寸的显著影响。在模拟的单太阳照射下,从浓度为 0.038 M、0.050 M 和 0.063 M 的 CH(3)NH(3)I 溶液中分别获得了 16.4%(s.d. ± 0.35)、16.3%(s.d. ± 0.44)和 13.5%(s.d. ± 0.34)的平均效率。通过控制 CH(3)NH(3)PbI(3) 长方体在生长过程中的尺寸,我们实现了最佳效率 17.01%,光电流密度为 21.64 mA cm(-2),开路光电压为 1.056 V,填充因子为 0.741。

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