State Key Laboratory of Bio-Organic and Natural Products Chemistry and Collaborative Innovation Center of Chemistry for life Sciences, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling Ling Road, Shanghai 200032, China.
J Am Chem Soc. 2015 Jun 3;137(21):6746-9. doi: 10.1021/jacs.5b03760. Epub 2015 May 18.
The rhodium-catalyzed asymmetric hydroboration of α-arylenamides with BI-DIME as the chiral ligand and (Bpin)2 as the reagent yields for the first time a series of α-amino tertiary boronic esters in good yields and excellent enantioselectivities (up to 99% ee).
铑催化的α-芳烯酰胺的不对称硼氢化反应，使用 BI-DIME 作为手性配体和 (Bpin)2 作为试剂，首次以良好的收率和优异的对映选择性（高达 99%ee）得到一系列α-氨基叔硼酸酯。
