碳-氟还原消除反应从镍（III）配合物。
Carbon-Fluorine Reductive Elimination from Nickel(III) Complexes.
机构信息
Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470, Mülheim an der Ruhr, Germany.
Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA, 02138, USA.
出版信息
Angew Chem Int Ed Engl. 2017 Jun 6;56(24):6966-6969. doi: 10.1002/anie.201701552. Epub 2017 May 11.
PMID:28493645
Abstract
We report a C-F reductive elimination from a characterized first-row aryl metal fluoride complex. Reductive elimination from the presented nickel(III) complexes is faster than C-F bond formation from any other characterized aryl metal fluoride complex.
摘要
我们报道了一个源自已确定的第一主族芳基金属氟化物配合物的 C-F 还原消除反应。与任何其他已确定的芳基金属氟化物配合物相比，所提出的镍（III）配合物的还原消除反应速度更快。
Zotero 插件