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嵌入Ni(OH)₂基质中的CeO₂纳米棒用于葡萄糖的非酶检测。

CeO₂ Nanorods Embedded in Ni(OH)₂ Matrix for the Non-Enzymatic Detection of Glucose.

作者信息

Li Yongjian, Guan Panpan, Yu Fucheng, Li Wei, Xie Xiaoling

机构信息

Department of Material Science, Taiyuan University of Technology, Taiyuan 030024, China.

School of Material Science, Lanzhou University of Technology, Lanzhou 730050, China.

出版信息

Nanomaterials (Basel). 2017 Jul 31;7(8):205. doi: 10.3390/nano7080205.

DOI:10.3390/nano7080205
PMID:28758973
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5575687/
Abstract

The electrode based on cerium oxide (CeO₂) nanorods embedded in nickel hydroxide (Ni(OH)₂) matrix were prepared and used for detecting glucose non-enzymatically. The materials were characterized by X-ray diffraction, transmission electron microscopy (TEM), and so on. The results indicate that the response of CeO₂/Ni(OH)₂ nanocomposite are significantly improved due to the synergetic effect between CeO₂ and Ni(OH)₂. The optimum CeO₂/Ni(OH)₂ nanocomposite electrode exhibits a detection range from 2 μM to 6.62 mM, a sensitivity of 594 μA mM cm, an estimated detection limit of 1.13 μM, and a response time less than 5 s. In addition, this biosensor also shows good selectivity, long term stability, and accurate measurement in juice on sale.

摘要

制备了基于嵌入氢氧化镍(Ni(OH)₂)基质中的氧化铈(CeO₂)纳米棒的电极,并将其用于非酶法检测葡萄糖。通过X射线衍射、透射电子显微镜(TEM)等对材料进行了表征。结果表明,由于CeO₂和Ni(OH)₂之间的协同效应,CeO₂/Ni(OH)₂纳米复合材料的响应显著提高。最佳的CeO₂/Ni(OH)₂纳米复合电极的检测范围为2 μM至6.62 mM,灵敏度为594 μA mM cm,估计检测限为1.13 μM,响应时间小于5 s。此外,该生物传感器在市售果汁中也表现出良好的选择性、长期稳定性和准确的测量结果。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/151b/5575687/a4040035fc83/nanomaterials-07-00205-g011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/151b/5575687/f630d644e897/nanomaterials-07-00205-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/151b/5575687/41e75b198d64/nanomaterials-07-00205-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/151b/5575687/a4040035fc83/nanomaterials-07-00205-g011.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/151b/5575687/e0a7017f4f5a/nanomaterials-07-00205-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/151b/5575687/1377760b25bc/nanomaterials-07-00205-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/151b/5575687/9c7d395c5370/nanomaterials-07-00205-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/151b/5575687/f630d644e897/nanomaterials-07-00205-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/151b/5575687/41e75b198d64/nanomaterials-07-00205-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/151b/5575687/a4040035fc83/nanomaterials-07-00205-g011.jpg

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