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来自阿法尔塞蒙(乳香树)精油的化学成分及单萜类对映体分布

Chemical Composition and Monoterpenoid Enantiomeric Distribution of the Essential Oils from Apharsemon (Commiphora gileadensis).

作者信息

Dudai Nativ, Shachter Alona, Satyal Prabodh, Setzer William N

机构信息

Agricultural Research Organization, Unit of Medicinal and Aromatic Plants, Newe Ya'ar Research Center, POB 1021, Ramat Yishay 30095, Israel.

Department of Chemistry, University of Alabama in Huntsville, Huntsville, AL 35899, USA.

出版信息

Medicines (Basel). 2017 Sep 12;4(3):66. doi: 10.3390/medicines4030066.

DOI:10.3390/medicines4030066
PMID:28930280
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5622401/
Abstract

(Hebrew: apharsemon) has been used since Biblical times to treat various ailments, and is used today in the traditional medicine of some Middle Eastern cultures. The essential oils from the stem bark, leaves, and fruits of -collected at the Ein Gedi Botanical Garden, Israel-were obtained by hydrodistillation and analyzed by gas chromatography-mass spectrometry. In addition, the enantiomeric distributions of the monoterpenoids in the essential oils have been determined by chiral gas chromatography. The essential oils were dominated by monoterpene hydrocarbons, followed by oxygenated monoterpenoids. The major components in oils were the monoterpenes α-pinene (11.1-18.4%), sabinene (15.8-35.9%), β-pinene (5.8-18.0%), -cymene (4.8-8.4%), limonene (1.3-6.2%), γ-terpinene (0.7-8.1%), and terpinen-4-ol (5.3-18.5%). The (-)-enantiomers predominated for α-pinene, sabinene, β-pinene, limonene, and terpinen-4-ol. The chemical compositions of the essential oils from Israel are markedly different from previously reported samples, which were rich in sesquiterpenoids. Likewise, the enantiomeric distribution of monoterpenoids is very different from spp. essential oils.

摘要

(希伯来语:apharsemon)自圣经时代起就被用于治疗各种疾病,如今在一些中东文化的传统医学中仍有应用。从以色列恩盖迪植物园采集的[植物名称]的茎皮、叶子和果实中提取的精油,通过水蒸馏法获得,并采用气相色谱 - 质谱联用仪进行分析。此外,通过手性气相色谱法测定了精油中单萜类化合物的对映体分布。精油以单萜烃类为主,其次是氧化单萜类化合物。[植物名称]精油中的主要成分是单萜类化合物α-蒎烯(11.1 - 18.4%)、桧烯(15.8 - 35.9%)、β-蒎烯(5.8 - 18.0%)、对异丙基甲苯(4.8 - 8.4%)、柠檬烯(1.3 - 6.2%)、γ-松油烯(0.7 - 8.1%)和萜品-4-醇(5.3 - 18.5%)。α-蒎烯、桧烯、β-蒎烯、柠檬烯和萜品-4-醇的(-)-对映体占主导。来自以色列的[植物名称]精油的化学成分与先前报道的富含倍半萜类化合物的样品明显不同。同样,单萜类化合物的对映体分布与[植物名称]属的精油也有很大差异。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5f34/5622401/7f74ae1726f0/medicines-04-00066-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5f34/5622401/021e8bacc128/medicines-04-00066-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5f34/5622401/7f74ae1726f0/medicines-04-00066-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5f34/5622401/021e8bacc128/medicines-04-00066-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5f34/5622401/7f74ae1726f0/medicines-04-00066-g002.jpg

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