sp C-H活化型导向基团。
sp C-H activation -type directing groups.
作者信息
Xu Yan, Dong Guangbin
机构信息
Department of Chemistry , University of Chicago , Chicago , Illinois 60637 , USA . Email:
出版信息
Chem Sci. 2018 Jan 17;9(6):1424-1432. doi: 10.1039/c7sc04768a. eCollection 2018 Feb 14.
Abstract
The application of -type directing groups (DGs) has led to the discovery of a wide range of novel C(sp)-H activation methods, which allow efficient and site-selective functionalization of alcohol and amide derivatives. In this mini-review we discuss the challenges of this field and summarize the achievements, including DG designs, reaction discoveries and mechanistic studies.
摘要
-型导向基团（DGs）的应用已促成了多种新型C(sp)-H活化方法的发现，这些方法能够实现醇和酰胺衍生物的高效及位点选择性官能团化。在本综述中，我们将探讨该领域面临的挑战，并总结所取得的成果，包括导向基团设计、反应发现及机理研究。
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