WPI-MANA , National Institute for Materials Science (NIMS) , 1-1 Namiki , Tsukuba 305-0044 , Japan.
Department of Advanced Materials Science, Graduate School of Frontier Sciences , The University of Tokyo , 5-1-5 Kashiwanoha , Kashiwa , Chiba 277-8561 , Japan.
Langmuir. 2019 Mar 12;35(10):3585-3599. doi: 10.1021/acs.langmuir.8b01434. Epub 2018 Jun 12.
Methodology to combine nanotechnology and these organization processes has been proposed as a novel concept of nanoarchitectonics, which can fabricate functional materials with nanolevel units. As an instant nanoarchitectonics approach, confining systems within a two-dimensional plane to drastically reduce translational motion freedom can be regarded as one of the rational approaches. Supramolecular chemistry and nanofabrication and their related functions at the air-water interface with the concept of nanoarchitectonics would lead to the creation of a novel methodology of Langmuir nanoarchitectonics. In this feature article, we briefly summarize research efforts related to Langmuir nanoarchitectonics including the basics for anomalies in molecular interactions such as highly enhanced molecular recognition capabilities. It is also extended to frontiers including the fabrication of supramolecular receptors and two-dimensional patterns with subnanometer-scale structural regulation, manual control of molecular machines and receptors by hand-motion-like macroscopic actions, and the regulation of cell fates at nanoarchitected arrays of nanocarbon assemblies and at direct liquid interfaces.
已经提出了将纳米技术和这些组织过程结合起来的方法学，作为一种新的纳米构筑学概念，可以用纳米级单元来制造功能材料。作为一种即时的纳米构筑学方法，可以在二维平面内限制系统，以大大降低平移运动自由度，可以被视为一种合理的方法。超分子化学和纳米制造及其在空气-水界面上的相关功能，结合纳米构筑学的概念，将导致朗缪尔纳米构筑学的新方法的产生。在这篇专题文章中，我们简要总结了与朗缪尔纳米构筑学相关的研究工作，包括分子相互作用异常的基础，如高度增强的分子识别能力。它还扩展到包括超分子受体和具有亚纳米尺度结构调节的二维图案的制造、通过类似手动的宏观动作对手动控制分子机器和受体、以及在纳米构筑的纳米碳组装阵列和直接液体界面处调节细胞命运。
