• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

锆辅助钯活化以促进甲烷干重整制合成气

Zirconium-Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming.

作者信息

Köpfle Norbert, Götsch Thomas, Grünbacher Matthias, Carbonio Emilia A, Hävecker Michael, Knop-Gericke Axel, Schlicker Lukas, Doran Andrew, Kober Delf, Gurlo Aleksander, Penner Simon, Klötzer Bernhard

机构信息

Institute of Physical Chemistry, University of Innsbruck, Innrain 52 c, 6020, Innsbruck, Austria.

Department of Inorganic Chemistry, Fritz-Haber-Institute of the Max-Planck-Society, Faradayweg 4-6, 14195, Berlin, Germany.

出版信息

Angew Chem Int Ed Engl. 2018 Oct 26;57(44):14613-14618. doi: 10.1002/anie.201807463. Epub 2018 Sep 17.

DOI:10.1002/anie.201807463
PMID:30179293
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6221108/
Abstract

C-saturated Pd nanoparticles with an extended phase boundary to ZrO evolve from a Pd Zr precatalyst under CH dry reforming conditions. This highly active catalyst state fosters bifunctional action: CO is efficiently activated at oxidic phase boundary sites and Pd C provides fast supply of C-atoms toward the latter.

摘要

在CH干重整条件下，具有与ZrO扩展相界的C饱和钯纳米颗粒由Pd-Zr预催化剂演变而来。这种高活性催化剂状态促进了双功能作用：CO在氧化相界位点被有效活化，而Pd-C为后者提供快速的C原子供应。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ec7/6221108/6c078a94cebc/ANIE-57-14613-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ec7/6221108/96e0f52ba253/ANIE-57-14613-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ec7/6221108/584ff0231988/ANIE-57-14613-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ec7/6221108/fed18d8c6e94/ANIE-57-14613-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ec7/6221108/6c078a94cebc/ANIE-57-14613-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ec7/6221108/96e0f52ba253/ANIE-57-14613-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ec7/6221108/584ff0231988/ANIE-57-14613-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ec7/6221108/fed18d8c6e94/ANIE-57-14613-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ec7/6221108/6c078a94cebc/ANIE-57-14613-g004.jpg

相似文献

1
Zirconium-Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming.锆辅助钯活化以促进甲烷干重整制合成气
Angew Chem Int Ed Engl. 2018 Oct 26;57(44):14613-14618. doi: 10.1002/anie.201807463. Epub 2018 Sep 17.
2
Chemical vapor deposition-prepared sub-nanometer Zr clusters on Pd surfaces: promotion of methane dry reforming.化学气相沉积法制备的钯表面亚纳米级锆簇：对甲烷干重整的促进作用
Phys Chem Chem Phys. 2016 Nov 23;18(46):31586-31599. doi: 10.1039/c6cp07197j.
3
Surface Spectroscopy on UHV-Grown and Technological Ni-ZrO Reforming Catalysts: From UHV to Operando Conditions.超高真空生长及工业用镍-氧化锆重整催化剂的表面光谱：从超高真空到原位条件
Top Catal. 2016;59(17):1614-1627. doi: 10.1007/s11244-016-0678-8. Epub 2016 Aug 12.
4
In situ NAP-XPS spectroscopy during methane dry reforming on ZrO/Pt(1 1 1) inverse model catalyst.在ZrO/Pt(1 1 1) 逆模型催化剂上进行甲烷干重整过程中的原位NAP-XPS光谱分析。
J Phys Condens Matter. 2018 Jul 4;30(26):264007. doi: 10.1088/1361-648X/aac6ff. Epub 2018 May 22.
5
Promotional effect of magnesium oxide for a stable nickel-based catalyst in dry reforming of methane.氧化镁对甲烷干重整中稳定镍基催化剂的促进作用。
Sci Rep. 2020 Aug 17;10(1):13861. doi: 10.1038/s41598-020-70930-1.
6
Rh/InGaNO nanoarchitecture for light-driven methane reforming with carbon dioxide toward syngas.用于光驱动二氧化碳甲烷重整制合成气的Rh/InGaNO纳米结构
Sci Bull (Beijing). 2024 May 30;69(10):1400-1409. doi: 10.1016/j.scib.2024.02.020. Epub 2024 Feb 12.
7
Zirconium Carbide Mediates Coke-Resistant Methane Dry Reforming on Nickel-Zirconium Catalysts.碳化锆在镍锆催化剂上介导抗焦甲烷干重整反应。
Angew Chem Int Ed Engl. 2022 Dec 12;61(50):e202213249. doi: 10.1002/anie.202213249. Epub 2022 Nov 15.
8
NiCo Nanocatalyst Supported by ZrO Hollow Sphere for Dry Reforming of Methane: Synergetic Catalysis by Ni and Co in Alloy.由ZrO空心球负载的NiCo纳米催化剂用于甲烷干重整：合金中Ni和Co的协同催化作用
ACS Appl Mater Interfaces. 2019 Jul 10;11(27):24078-24087. doi: 10.1021/acsami.9b05822. Epub 2019 Jun 25.
9
Dry reforming of methane to syngas: a potential alternative process for value added chemicals-a techno-economic perspective.甲烷干重整制合成气：从技术经济角度看，一种生产增值化学品的潜在替代工艺
Environ Sci Pollut Res Int. 2016 Nov;23(22):22267-22273. doi: 10.1007/s11356-016-6310-4. Epub 2016 Mar 4.
10
Ni@ZrO yolk-shell catalyst for CO methane reforming: Effect of Ni@SiO size as the hard-template.用于CO甲烷重整的Ni@ZrO核壳催化剂：以Ni@SiO尺寸作为硬模板的影响
J Colloid Interface Sci. 2021 May 15;590:641-651. doi: 10.1016/j.jcis.2021.01.100. Epub 2021 Feb 2.

引用本文的文献

1
The role of Co-GaO interfaces in methane dry reforming.钴 - 氧化镓界面在甲烷干重整中的作用。
Catal Sci Technol. 2025 May 7;15(12):3667-3680. doi: 10.1039/d5cy00179j. eCollection 2025 Jun 16.
2
Regeneration of Ni-Zr Methane Dry Reforming Catalysts in CO: Reduction of Coking and Ni Redispersion.镍-锆甲烷干重整催化剂在一氧化碳中的再生：减少积炭和镍的再分散
ACS Catal. 2025 Feb 10;15(4):3314-3327. doi: 10.1021/acscatal.4c06230. eCollection 2025 Feb 21.
3
Facilitating the dry reforming of methane with interfacial synergistic catalysis in an Ir@CeO catalyst.

本文引用的文献

1
In situ NAP-XPS spectroscopy during methane dry reforming on ZrO/Pt(1 1 1) inverse model catalyst.在ZrO/Pt(1 1 1) 逆模型催化剂上进行甲烷干重整过程中的原位NAP-XPS光谱分析。
J Phys Condens Matter. 2018 Jul 4;30(26):264007. doi: 10.1088/1361-648X/aac6ff. Epub 2018 May 22.
2
Role of Precursor Carbides for Graphene Growth on Ni(111).前驱体碳化物在Ni(111)上石墨烯生长中的作用
Sci Rep. 2018 Feb 8;8(1):2662. doi: 10.1038/s41598-018-20777-4.
3
Contrasting the Role of Ni/AlO Interfaces in Water-Gas Shift and Dry Reforming of Methane.
采用Ir@CeO催化剂通过界面协同催化促进甲烷干重整。
Nat Commun. 2024 May 4;15(1):3765. doi: 10.1038/s41467-024-48122-6.
4
Zirconium Carbide Mediates Coke-Resistant Methane Dry Reforming on Nickel-Zirconium Catalysts.碳化锆在镍锆催化剂上介导抗焦甲烷干重整反应。
Angew Chem Int Ed Engl. 2022 Dec 12;61(50):e202213249. doi: 10.1002/anie.202213249. Epub 2022 Nov 15.
5
Who Does the Job? How Copper Can Replace Noble Metals in Sustainable Catalysis by the Formation of Copper-Mixed Oxide Interfaces.谁来完成这项工作？铜如何通过形成铜混合氧化物界面在可持续催化中取代贵金属。
ACS Catal. 2022 Jul 1;12(13):7696-7708. doi: 10.1021/acscatal.2c01584. Epub 2022 Jun 14.
6
Elucidating the role of earth alkaline doping in perovskite-based methane dry reforming catalysts.阐明碱土金属掺杂在钙钛矿基甲烷干重整催化剂中的作用。
Catal Sci Technol. 2022 Jan 6;12(4):1229-1244. doi: 10.1039/d1cy02044g. eCollection 2022 Feb 21.
7
Atomic-Scale Insights into Nickel Exsolution on LaNiO Catalysts via Electron Microscopy.通过电子显微镜对LaNiO催化剂上镍析出的原子尺度洞察。
J Phys Chem C Nanomater Interfaces. 2022 Jan 13;126(1):786-796. doi: 10.1021/acs.jpcc.1c09257. Epub 2021 Dec 30.
8
Steering the methanol steam reforming reactivity of intermetallic Cu-In compounds by redox activation: stability formation of an intermetallic compound-oxide interface.通过氧化还原活化调控金属间Cu-In化合物的甲醇蒸汽重整反应活性：金属间化合物-氧化物界面的稳定性形成
Catal Sci Technol. 2021 Jul 23;11(16):5518-5533. doi: 10.1039/d1cy00913c. eCollection 2021 Aug 16.
9
Steering the Catalytic Properties of Intermetallic Compounds and Alloys in Reforming Reactions by Controlled Decomposition and Self-Activation.通过可控分解和自活化调控金属间化合物及合金在重整反应中的催化性能
ACS Catal. 2021 May 7;11(9):5271-5286. doi: 10.1021/acscatal.1c00718. Epub 2021 Apr 16.
10
Steering the Methane Dry Reforming Reactivity of Ni/LaO Catalysts by Controlled In Situ Decomposition of Doped LaNiO Precursor Structures.通过掺杂LaNiO前驱体结构的可控原位分解调控Ni/LaO催化剂的甲烷干重整反应活性
ACS Catal. 2021 Jan 1;11(1):43-59. doi: 10.1021/acscatal.0c04290. Epub 2020 Dec 11.
对比 Ni/AlO 界面在水煤气变换和甲烷干重整反应中的作用。
J Am Chem Soc. 2017 Nov 29;139(47):17128-17139. doi: 10.1021/jacs.7b08984. Epub 2017 Nov 14.
4
CO Reduction on the Pre-reduced Mixed Ionic-Electronic Conducting Perovskites La Sr FeO and SrTi Fe O.预还原混合离子电子导电钙钛矿LaSrFeO和SrTiFeO上的CO还原
Chemphyschem. 2018 Jan 5;19(1):93-107. doi: 10.1002/cphc.201700970. Epub 2017 Nov 28.
5
Surface Chemistry of Perovskite-Type Electrodes During High Temperature CO Electrolysis Investigated by Operando Photoelectron Spectroscopy.钙钛矿型电极在高温 CO 电解过程中的表面化学 通过 operando 光电子能谱研究。
ACS Appl Mater Interfaces. 2017 Oct 18;9(41):35847-35860. doi: 10.1021/acsami.7b10673. Epub 2017 Oct 5.
6
Chemical vapor deposition-prepared sub-nanometer Zr clusters on Pd surfaces: promotion of methane dry reforming.化学气相沉积法制备的钯表面亚纳米级锆簇：对甲烷干重整的促进作用
Phys Chem Chem Phys. 2016 Nov 23;18(46):31586-31599. doi: 10.1039/c6cp07197j.
7
Surface chemistry and catalysis confined under two-dimensional materials.二维材料限域下的表面化学与催化。
Chem Soc Rev. 2017 Apr 3;46(7):1842-1874. doi: 10.1039/c6cs00424e.
8
Catalysis with two-dimensional materials and their heterostructures.二维材料及其异质结构的催化作用。
Nat Nanotechnol. 2016 Mar;11(3):218-30. doi: 10.1038/nnano.2015.340.
9
A review of dry (CO2) reforming of methane over noble metal catalysts.关于贵金属催化剂上甲烷干（CO2）重整的综述。
Chem Soc Rev. 2014 Nov 21;43(22):7813-37. doi: 10.1039/c3cs60395d.
10
Pd-Au bimetallic catalysts: understanding alloy effects from planar models and (supported) nanoparticles.钯金双金属催化剂：从平面模型和（负载型）纳米颗粒理解合金效应。
Chem Soc Rev. 2012 Dec 21;41(24):8009-20. doi: 10.1039/c2cs35160a.