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麻疯树介导的氧化铜纳米粒子的绿色合成:一种有前途的环保可持续材料,可用于废水处理和高效抗菌剂。

Madhuca longifolia plant mediated green synthesis of cupric oxide nanoparticles: A promising environmentally sustainable material for waste water treatment and efficient antibacterial agent.

机构信息

Materials Research Laboratory, Department of Chemistry, The University of Burdwan, Golapbag, Burdwan 713104, West Bengal, India.

Department of Microbiology, The University of Burdwan, Burdwan 713104, West Bengal, India.

出版信息

J Photochem Photobiol B. 2018 Dec;189:66-73. doi: 10.1016/j.jphotobiol.2018.09.023. Epub 2018 Oct 3.

Abstract

In current years, the development of efficient green methods for synthesis of metal oxide nanomaterials has attracted a great attention to the researchers since the plant-mediated synthesis is a cost-effective and a good alternative to chemical and physical methods. An efficient and eco-friendly route has been developed for the green synthesis of CuO nanoparticles (NPs) by Madhuca longifolia plant extract which acts as a non-toxic reducing agent. X-ray diffraction studies reveal the good crystallinity of the synthesized NPs and FTIR spectra confirm the synthesis of these NPs. UV-visible absorption spectra showed that the NPs have been reached at different nano scale level depending on their synthesis procedures. TEM images indicate that as-synthesized CuO NPs are spherical in shape with their different size ranges and they show different band gap values which is confirmed by Tauc's formula. The NPs exhibit good photoluminescence property depending on their particle size and they also show excellent photocatalytic activity towards the degradation of methylene blue (MB) in presence of visible light irradiation which will be a promising material for waste water treatment. The synthesized CuO NPs show good antibacterial activity against bacterial strains namely E. coli BL21 DE3 Gram-negative, S. aureus Gram-positive and B.subtilis Gram-positive and the results have been compared against Ampicillin and Tetracycline.

摘要

近年来,由于植物介导的合成方法是化学和物理方法的一种具有成本效益的替代方法,因此,开发用于合成金属氧化物纳米材料的高效绿色方法引起了研究人员的极大关注。通过 Madhuca longifolia 植物提取物开发了一种绿色合成氧化铜纳米颗粒 (NPs) 的有效且环保的方法,该植物提取物可作为无毒还原剂。X 射线衍射研究表明合成的 NPs 具有良好的结晶度,傅里叶变换红外光谱证实了这些 NPs 的合成。紫外-可见吸收光谱表明,根据其合成程序,这些 NPs 已达到不同的纳米级水平。TEM 图像表明,所合成的 CuO NPs 呈球形,具有不同的尺寸范围,并且它们表现出不同的带隙值,这通过 Tauc 公式得到了证实。这些 NPs 表现出良好的光致发光性能,这取决于它们的粒径,并且它们在可见光照射下对亚甲基蓝 (MB) 的降解表现出优异的光催化活性,这将是一种有前途的废水处理材料。所合成的 CuO NPs 对细菌菌株(即革兰氏阴性的大肠杆菌 BL21 DE3、革兰氏阳性的金黄色葡萄球菌和革兰氏阳性的枯草芽孢杆菌)表现出良好的抗菌活性,并且将其与氨苄青霉素和四环素进行了比较。

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