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CdSe量子点的快速诱导与微波加热合成

Rapid Induction and Microwave Heat-Up Syntheses of CdSe Quantum Dots.

作者信息

Luo Hongfu, Kebede Bemnet A, McLaurin Emily J, Chikan Viktor

机构信息

Department of Chemistry, Kansas State University, 213 CBC Building, 1212 Mid-Campus Dr North, Manhattan, Kansas 66506-0401, United States.

出版信息

ACS Omega. 2018 May 21;3(5):5399-5405. doi: 10.1021/acsomega.8b00096. eCollection 2018 May 31.

Abstract

The production of nanoparticles on an industrial scale requires an approach other than the widely used hot-injection method. In this work, two heat-up methods are applied to nanoparticle synthesis. The induction heating method produces CdSe quantum dots with ultrasmall properties in seconds. Initial flow-through experiments demonstrate that induction heating continuously produces quantum dots. These results are compared with those from microwave synthesis, which produces quantum dots on a longer timescale but provides fast, continuous heating. Both methods can produce quantum dots within seconds because of rapid heating. In addition, different precursors, single source and separate source, give different results, ultimately providing a handle to control quantum dot properties.

摘要

在工业规模上生产纳米颗粒需要一种不同于广泛使用的热注射法的方法。在这项工作中,两种加热方法被应用于纳米颗粒的合成。感应加热法能在几秒钟内制备出具有超小特性的CdSe量子点。初步的流通实验表明感应加热能持续产生量子点。这些结果与微波合成法的结果进行了比较,微波合成法在更长的时间尺度上产生量子点,但能提供快速、持续的加热。由于快速加热,这两种方法都能在几秒钟内产生量子点。此外,不同的前驱体,单源和分源,会产生不同的结果,最终为控制量子点的性质提供了一种手段。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b0af/6641973/4bb3b32fc7f1/ao-2018-00096m_0001.jpg

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