Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 211816, P. R. China.
Cambridge Graphene Centre, University of Cambridge, Cambridge CB3 0FA, UK.
Chem Soc Rev. 2020 Mar 21;49(6):1756-1789. doi: 10.1039/c9cs00459a. Epub 2020 Feb 17.
The rapid development of the Internet of Things (IoT)-enabled applications and connected automation are increasingly making sensing technologies the heart of future intelligent systems. The potential applications have wide-ranging implications, from industrial manufacturing and chemical process control to agriculture and nature conservation, and even to personal health monitoring, smart cities, and national defence. Devices that can detect trace amounts of analyte gases represent the most ubiquitous of these sensor platforms. In particular, the advent of nanostructured organic and inorganic materials has significantly transformed this field. Highly sensitive, selective, and portable sensing devices are now possible due to the large surface to volume ratios, favorable transport properties and tunable surface chemistry of the sensing materials. Here, we present a review on the recent development of printed gas sensors. We first introduce the state-of-the-art printing techniques, and then describe a variety of gas sensing materials including metal oxides, conducting polymers, carbon nanotubes and two-dimensional (2D) materials. Particular emphases are given to the working principles of the printing techniques and sensing mechanisms of the different material systems. Strategies that can improve sensor performance via materials design and device fabrication are discussed. Finally, we summarize the current challenges and present our perspectives in opportunities in the future development of printed gas sensors.
物联网 (IoT) 应用和连接自动化的快速发展,使得传感技术日益成为未来智能系统的核心。潜在的应用具有广泛的影响,从工业制造和化学过程控制到农业和自然保护,甚至个人健康监测、智能城市和国防。能够检测痕量分析物气体的设备代表了这些传感器平台中最普遍的设备。特别是,纳米结构有机和无机材料的出现极大地改变了这一领域。由于传感材料的大表面积与体积比、有利的传输特性和可调谐的表面化学,现在可以实现高灵敏度、选择性和便携式传感设备。在这里,我们对印刷气体传感器的最新发展进行了综述。我们首先介绍了最先进的印刷技术,然后描述了各种气体传感材料,包括金属氧化物、导电聚合物、碳纳米管和二维 (2D) 材料。特别强调了印刷技术的工作原理和不同材料系统的传感机制。讨论了通过材料设计和器件制造来提高传感器性能的策略。最后,我们总结了当前的挑战,并提出了我们对未来印刷气体传感器发展的看法和机遇。