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关于二氧化硅、碳和磁性材料负载的铜物种作为“点击”反应中高效非均相纳米催化剂的系统综述。

A systematic review on silica-, carbon-, and magnetic materials-supported copper species as efficient heterogeneous nanocatalysts in "click" reactions.

作者信息

Shiri Pezhman, Aboonajmi Jasem

机构信息

Department of Chemistry, Shiraz University, Shiraz, Iran.

出版信息

Beilstein J Org Chem. 2020 Apr 1;16:551-586. doi: 10.3762/bjoc.16.52. eCollection 2020.

Abstract

In recent years, many inorganic silica/carbon-based and magnetic materials have been selected to arrest copper ions through a widespread range of anchoring and embedding methodologies. These inorganic supported nanocatalysts have been found to be efficient, environmentally friendly, recyclable, and durable. In addition, one of the vital issues for expanding new, stable, and reusable catalysts is the discovery of unique catalysts. The basis and foundation of this review article is to consider the recently published developments (2014-2019) in the synthesis and catalytic applications of copper supported by silica nanocomposites, carbon nanocomposites, and magnetic nanocomposites for expanding the "click" chemistry.

摘要

近年来,人们通过广泛的锚定和嵌入方法,选用了许多无机二氧化硅/碳基和磁性材料来捕获铜离子。这些无机负载型纳米催化剂已被证明具有高效、环保、可回收和耐用的特点。此外,开发新型、稳定且可重复使用的催化剂的一个关键问题是发现独特的催化剂。本文综述的依据和基础是考虑最近发表的(2014 - 2019年)关于二氧化硅纳米复合材料、碳纳米复合材料和磁性纳米复合材料负载铜的合成及催化应用方面的进展,以拓展“点击”化学。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5544/7136568/09beccc59959/Beilstein_J_Org_Chem-16-551-g025.jpg

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