• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

全π共轭聚合物、树枝状大分子和低聚物中的聚集诱导发光特性。

Aggregation-Induced Emission Properties in Fully π-Conjugated Polymers, Dendrimers, and Oligomers.

作者信息

Sánchez-Ruiz Antonio, Sousa-Hervés Ana, Tolosa Barrilero Juan, Navarro Amparo, Garcia-Martinez Joaquín C

机构信息

Facultad de Farmacia, Departamento de Química Inorgánica Orgánica y Bioquímica, Universidad de Castilla-La Mancha, C/José María Sánchez Ibáñez s/n, 02008 Albacete, Spain.

Regional Center for Biomedical Research (CRIB), Universidad de Castilla-La Mancha, C/Almansa 13, 02008 Albacete, Spain.

出版信息

Polymers (Basel). 2021 Jan 9;13(2):213. doi: 10.3390/polym13020213.

DOI:10.3390/polym13020213
PMID:33435293
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7826689/
Abstract

Aggregation-Induced Emission (AIE) in organic molecules has recently attracted the attention of the scientific community because of their potential applications in different fields. Compared to small molecules, little attention has been paid to polymers and oligomers that exhibit AIE, despite having excellent properties such as high emission efficiency in aggregate and solid states, signal amplification effect, good processability and the availability of multiple functionalization sites. In addition to these features, if the molecular structure is fully conjugated, intramolecular electronic interactions between the composing chromophores may appear, thus giving rise to a wealth of new photophysical properties. In this review, we focus on selected fully conjugated oligomers, dendrimers and polymers, and briefly summarize their synthetic routes, fluorescence properties and potential applications. An exhaustive comparison between spectroscopic results in solution and aggregates or in solid state has been collected in almost all examples, and an opinion on the future direction of the field is briefly stated.

摘要

有机分子中的聚集诱导发光（AIE）由于其在不同领域的潜在应用，近来引起了科学界的关注。与小分子相比，具有AIE特性的聚合物和低聚物尽管具有诸如在聚集态和固态下的高发射效率、信号放大效应、良好的加工性能以及多个功能化位点等优异性能，但受到的关注较少。除了这些特性外，如果分子结构是完全共轭的，组成发色团之间可能会出现分子内电子相互作用，从而产生丰富的新光物理性质。在这篇综述中，我们聚焦于选定的完全共轭低聚物、树枝状大分子和聚合物，并简要总结它们的合成路线、荧光性质和潜在应用。几乎在所有实例中都收集了溶液与聚集体或固态光谱结果之间的详尽比较，并简要阐述了对该领域未来方向的看法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/d93c06162a9f/polymers-13-00213-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/d59e198de190/polymers-13-00213-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/4229d88af699/polymers-13-00213-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/afb2c3c41125/polymers-13-00213-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/dbb76b4ae01c/polymers-13-00213-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/4aeebde6636f/polymers-13-00213-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/077c9a6882f5/polymers-13-00213-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/9253098224e7/polymers-13-00213-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/3a9ccae8d5a6/polymers-13-00213-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/05d9a9ebb1d0/polymers-13-00213-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/9f33d6d0fdc6/polymers-13-00213-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/716b82333d5a/polymers-13-00213-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/ce690a448147/polymers-13-00213-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/29790ee78cd7/polymers-13-00213-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/d08f442246ca/polymers-13-00213-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/2979fcadf82c/polymers-13-00213-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/b30a122faa15/polymers-13-00213-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/39d0771af821/polymers-13-00213-g021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/d93c06162a9f/polymers-13-00213-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/d59e198de190/polymers-13-00213-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/4229d88af699/polymers-13-00213-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/afb2c3c41125/polymers-13-00213-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/dbb76b4ae01c/polymers-13-00213-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/4aeebde6636f/polymers-13-00213-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/077c9a6882f5/polymers-13-00213-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/9253098224e7/polymers-13-00213-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/3a9ccae8d5a6/polymers-13-00213-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/05d9a9ebb1d0/polymers-13-00213-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/9f33d6d0fdc6/polymers-13-00213-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/716b82333d5a/polymers-13-00213-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/ce690a448147/polymers-13-00213-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/29790ee78cd7/polymers-13-00213-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/d08f442246ca/polymers-13-00213-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/2979fcadf82c/polymers-13-00213-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/b30a122faa15/polymers-13-00213-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/39d0771af821/polymers-13-00213-g021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56dc/7826689/d93c06162a9f/polymers-13-00213-g023.jpg

相似文献

1
Aggregation-Induced Emission Properties in Fully π-Conjugated Polymers, Dendrimers, and Oligomers.全π共轭聚合物、树枝状大分子和低聚物中的聚集诱导发光特性。
Polymers (Basel). 2021 Jan 9;13(2):213. doi: 10.3390/polym13020213.
2
Synthetic Regulation of 1,4-Dihydropyridines for the AIE or AIEE Effect: From Rational Design to Mechanistic Views.用于聚集诱导发光（AIE）或聚集诱导发光增强（AIEE）效应的1,4-二氢吡啶的合成调控：从合理设计到机理研究
Chemistry. 2018 Apr 3;24(19):4871-4878. doi: 10.1002/chem.201705269. Epub 2018 Mar 2.
3
Aggregation behaviour of pyrene-based luminescent materials, from molecular design and optical properties to application.基于芘的发光材料的聚集行为，从分子设计、光学性质到应用
Chem Soc Rev. 2023 Oct 2;52(19):6715-6753. doi: 10.1039/d3cs00251a.
4
Efficient deep blue emission by 4-styrylbenzonitrile derivatives in solid state: Synthesis, aggregation induced emission characteristics and crystal structures.高效深蓝光发射的 4-苯乙烯基苯甲腈衍生物在固态下：合成、聚集诱导发光特性和晶体结构。
Spectrochim Acta A Mol Biomol Spectrosc. 2022 Feb 15;267(Pt 2):120575. doi: 10.1016/j.saa.2021.120575. Epub 2021 Nov 2.
5
Fluorescent Polymers Conspectus.荧光聚合物概论
Polymers (Basel). 2022 Mar 11;14(6):1118. doi: 10.3390/polym14061118.
6
Probing the pi-stacking induced molecular aggregation in pi-conjugated polymers, oligomers, and their blends of p-phenylenevinylenes.探究π共轭聚合物、低聚物及其对亚苯基乙烯基低聚物共混物中π堆积诱导的分子聚集。
J Phys Chem B. 2008 Jan 31;112(4):1119-29. doi: 10.1021/jp077404z. Epub 2008 Jan 8.
7
Aggregation-Induced Emission: From Small Molecules to Polymers-Historical Background, Mechanisms and Photophysics.聚集诱导发光：从小分子到聚合物——历史背景、机理与光物理学
Top Curr Chem (Cham). 2021 Mar 16;379(3):15. doi: 10.1007/s41061-021-00327-9.
8
Stimuli-Responsive Aggregation-Induced Emission (AIE)-Active Polymers for Biomedical Applications.刺激响应聚集诱导发光（AIE）活性聚合物在生物医学中的应用。
ACS Biomater Sci Eng. 2022 Oct 10;8(10):4207-4229. doi: 10.1021/acsbiomaterials.2c00656. Epub 2022 Sep 2.
9
The Marriage of Aggregation-Induced Emission with Polymer Science.聚集诱导发光与高分子科学的联姻。
Macromol Rapid Commun. 2019 Jan;40(1):e1800568. doi: 10.1002/marc.201800568. Epub 2018 Sep 25.
10
Bringing Inherent Charges into Aggregation-Induced Emission Research.将固有电荷引入聚集诱导发光研究中。
Acc Chem Res. 2022 Jan 18;55(2):197-208. doi: 10.1021/acs.accounts.1c00630. Epub 2022 Jan 5.

引用本文的文献

1
Fluorescent polymer as a biosensing tool for the diagnosis of microbial pathogens.荧光聚合物作为诊断微生物病原体的生物传感工具。
Sci Rep. 2024 Jan 25;14(1):2203. doi: 10.1038/s41598-024-51919-6.
2
Dye Modified Phenylenediamine Oligomers: Theoretical Studies on Drug Binding for Their Potential Application in Drug Sensors.染料修饰的苯二胺低聚物：用于药物传感器潜在应用的药物结合理论研究。
ACS Phys Chem Au. 2023 Aug 28;3(6):521-531. doi: 10.1021/acsphyschemau.3c00025. eCollection 2023 Nov 22.
3
Polymers and Polymer-Based Materials for the Detection of (Nitro-)explosives.

本文引用的文献

1
In Situ Water-Compatible Polymer Entrapment: A Strategy for Transferring Superhydrophobic Microporous Organic Polymers to Water.原位水相容性聚合物包封：一种将超疏水微孔有机聚合物转移到水中的策略。
ACS Macro Lett. 2018 Jun 19;7(6):651-655. doi: 10.1021/acsmacrolett.8b00263. Epub 2018 May 18.
2
Synthesis of tetraphenylethylene-based conjugated microporous polymers for detection of nitroaromatic explosive compounds.用于检测硝基芳香族爆炸化合物的基于四苯乙烯的共轭微孔聚合物的合成。
RSC Adv. 2018 Oct 5;8(60):34291-34296. doi: 10.1039/c8ra06463f. eCollection 2018 Oct 4.
3
Synthesis, chiroptical properties, and self-assembled nanoparticles of chiral conjugated polymers based on optically stable helical aromatic esters.
用于检测（硝基）炸药的聚合物及聚合物基材料。
Materials (Basel). 2023 Sep 21;16(18):6333. doi: 10.3390/ma16186333.
4
Fluorescent and Magnetic Radical Dendrimers as Potential Bimodal Imaging Probes.荧光与磁性自由基树枝状大分子作为潜在的双模态成像探针
Pharmaceutics. 2023 Jun 20;15(6):1776. doi: 10.3390/pharmaceutics15061776.
5
Fluorescent Polymers Conspectus.荧光聚合物概论
Polymers (Basel). 2022 Mar 11;14(6):1118. doi: 10.3390/polym14061118.
6
A Brief Overview of Polymers Science and Technology, in Spain.西班牙聚合物科学与技术概述
Polymers (Basel). 2022 Feb 9;14(4):652. doi: 10.3390/polym14040652.
7
A New Year's Message 2022.2022年新年致辞
Polymers (Basel). 2022 Jan 27;14(3):500. doi: 10.3390/polym14030500.
8
Molecular Encapsulation of Naphthalene Diimide (NDI) Based π-Conjugated Polymers: A Tool for Understanding Photoluminescence.基于萘二亚胺（NDI）的π共轭聚合物的分子封装：一种理解光致发光的工具。
Angew Chem Int Ed Engl. 2021 Nov 15;60(47):25005-25012. doi: 10.1002/anie.202110139. Epub 2021 Oct 18.
基于光学稳定螺旋芳酯的手性共轭聚合物的合成、手性光学性质及自组装纳米颗粒
RSC Adv. 2018 Jan 3;8(2):1014-1021. doi: 10.1039/c7ra12652b. eCollection 2018 Jan 2.
4
Synthesis of π-conjugated network polymers based on triphenylamine (TPA) and tetraphenylethylene (TPE) as building blocks direct Pd-catalyzed reactions and their application in CO capture and explosive detection.基于三苯胺（TPA）和四苯乙烯（TPE）作为构建单元的π共轭网络聚合物的合成、直接钯催化反应及其在CO捕获和爆炸物检测中的应用。
RSC Adv. 2019 Jun 10;9(32):18098-18105. doi: 10.1039/c9ra02469g.
5
Rational design of a high-efficiency, multivariate metal-organic framework phosphor for white LED bulbs.用于白光发光二极管灯泡的高效多变量金属有机框架磷光体的合理设计。
Chem Sci. 2020 Jan 10;11(7):1814-1824. doi: 10.1039/c9sc05721h.
6
Shedding Light on the Origin of Solid-State Luminescence Enhancement in Butterfly Molecules.揭示蝶状分子中固态发光增强的起源。
Chemistry. 2020 Nov 2;26(61):13990-14001. doi: 10.1002/chem.202002920. Epub 2020 Sep 30.
7
Biotinylated platinum(ii) metallacage towards targeted cancer theranostics.生物素化铂（II）金属笼用于靶向癌症治疗学。
Chem Commun (Camb). 2020 Jul 28;56(60):8460-8463. doi: 10.1039/d0cc03824e.
8
Understanding the Driving Mechanisms of Enhanced Luminescence Emission of Oligo(styryl)benzenes and Tri(styryl)-s-triazine.理解寡聚（苯乙烯基）苯和三（苯乙烯基）-s-三嗪增强发光发射的驱动机制。
Chemistry. 2020 Mar 12;26(15):3373-3384. doi: 10.1002/chem.201905336. Epub 2020 Feb 19.
9
Emissive Platinum(II) Cages with Reverse Fluorescence Resonance Energy Transfer for Multiple Sensing.发射态铂（II）笼合物的反向荧光共振能量转移及其多重传感。
J Am Chem Soc. 2020 Feb 5;142(5):2592-2600. doi: 10.1021/jacs.9b12689. Epub 2020 Jan 27.
10
Pressure-Induced Multiphoton Excited Fluorochromic Metal-Organic Frameworks for Improving MPEF Properties.用于改善多光子激发荧光特性的压力诱导多光子激发荧光金属有机框架
Angew Chem Int Ed Engl. 2019 Oct 1;58(40):14379-14385. doi: 10.1002/anie.201908793. Epub 2019 Aug 19.