Huang Xi, Zhou Xin, Dai Qingyin, Qin Zhiyong
School of Resources, Environment, and Materials, Guangxi University, Nanning 530000, China.
MOE Key Laboratory of New Processing Technology for Non-Ferrous Metals and Materials, Nanning 530000, China.
Nanomaterials (Basel). 2021 Dec 8;11(12):3337. doi: 10.3390/nano11123337.
The objective of this study was to prepare a functional biodegradable soy protein isolate (SPI) food packaging film by introducing a natural antimicrobial agent, mangosteen peel extract (MPE, 10 wt% based on SPI), and different concentrations of functional modifiers, ZnO NPs, into the natural polymer SPI by solution casting method. The physical, antioxidant, antibacterial properties and chemical structures were also investigated. The composite film with 5% ZnO NPs had the maximum tensile strength of 8.84 MPa and the lowest water vapor transmission rate of 9.23 g mm/m h Pa. The composite film also exhibited excellent UV-blocking, antioxidant, and antibacterial properties against and . The TGA results showed that the introduction of MPE and ZnO NPs improved the thermal stability of SPI films. The microstructure of the films was analyzed by SEM to determine the smooth surface of the composite films. ATR-FTIR and XPS analyses demonstrated the strong hydrogen bonding of SPI, MPE, and ZnO NPs in the films. The presence of ZnO NPs in the composite films was also proved by EDX and XRD. These results suggest that SPI/MPE/ZnO composite film is promising for food-active packaging to extend the shelf life of food products.
本研究的目的是通过溶液浇铸法,将天然抗菌剂山竹果皮提取物(MPE,基于SPI的10 wt%)和不同浓度的功能改性剂ZnO纳米颗粒引入天然聚合物大豆分离蛋白(SPI)中,制备一种功能性可生物降解的大豆分离蛋白食品包装薄膜。同时还研究了其物理性能、抗氧化性能、抗菌性能和化学结构。含有5%ZnO纳米颗粒的复合薄膜具有8.84 MPa的最大拉伸强度和9.23 g mm/m h Pa的最低水蒸气透过率。该复合薄膜还对[具体菌种1]和[具体菌种2]表现出优异的紫外线阻隔、抗氧化和抗菌性能。热重分析(TGA)结果表明,MPE和ZnO纳米颗粒的引入提高了SPI薄膜的热稳定性。通过扫描电子显微镜(SEM)分析薄膜的微观结构,以确定复合薄膜表面的光滑度。衰减全反射傅里叶变换红外光谱(ATR-FTIR)和X射线光电子能谱(XPS)分析表明,SPI、MPE和ZnO纳米颗粒在薄膜中形成了强氢键。能量色散X射线光谱(EDX)和X射线衍射(XRD)也证明了复合薄膜中ZnO纳米颗粒的存在。这些结果表明,SPI/MPE/ZnO复合薄膜在食品活性包装方面具有广阔前景,可延长食品的保质期。