Yu Zhihao, Ji Na, Li Xiaoyun, Zhang Rui, Qiao Yina, Xiong Jian, Liu Jian, Lu Xuebin
School of Environmental Science and Engineering, Tianjin University, Tianjin, 300350, P.R. China.
School of Agriculture, Sun Yat-Sen University, Guangdong, 510275, P.R. China.
Angew Chem Int Ed Engl. 2023 Jan 16;62(3):e202213612. doi: 10.1002/anie.202213612. Epub 2022 Dec 7.
As a novel class of catalytic materials, hollow nanoreactors offer new opportunities for improving catalytic performance owing to their higher controllability on molecular kinetic behavior. Nevertheless, to achieve controllable catalysis with specific purposes, the catalytic mechanism occurring inside hollow nanoreactors remains to be further understood. In this context, this Review presents a focused discussion about the basic concept of hollow nanoreactors, the underlying theory for hollow nanoreactor-driven kinetics, and the intrinsic correlation between key structural parameters of hollow nanoreactors and molecular kinetic behaviors. We aim to provide in-depth insights into understanding kinetics occurred within typical hollow nanoreactors. The perspectives proposed in this paper may contribute to the development of the fundamental theoretical framework of hollow nanoreactor-driven catalysis.
作为一类新型催化材料，中空纳米反应器因其对分子动力学行为具有更高的可控性，为提高催化性能提供了新机遇。然而，为实现特定目的的可控催化，中空纳米反应器内部发生的催化机制仍有待进一步了解。在此背景下，本综述聚焦讨论中空纳米反应器的基本概念、中空纳米反应器驱动动力学的基础理论，以及中空纳米反应器关键结构参数与分子动力学行为之间的内在关联。我们旨在深入洞察典型中空纳米反应器内发生的动力学过程。本文提出的观点可能有助于中空纳米反应器驱动催化基本理论框架的发展。
