College of Vocational and Technical Education, Yunnan Normal University, Kunming, P.R. China.
Central Laboratory, Yunnan Institute of Traditional Chinese Medicine and Materia Medica, Kunming, P.R. China.
Nat Prod Res. 2024 May;38(9):1524-1530. doi: 10.1080/14786419.2022.2155645. Epub 2022 Dec 9.
Two new degrade cycloartane triterpenoids, named buboditones A, B (, ), together with ten known alkaloids, cyclobuxoviridine (), -dimethylcycloxobuxovircine (), cyclovirobuxine C (), cyclovirobuxine A (), cycloprotobuxine C (), cycloprotobuxine A (), cyclobuxoxazine (), cyclobuxoxazine A (), buxruguline B (), irehine (), were isolated from the leaves and stems of Levl., The structures of compounds were elucidated by 1 D and 2 D NMR spectroscopic methods including HSQC, HMBC, H-H COSY, NOESY, as well as HRESIMS spectroscopic analysis.
从 Levl. 的叶和茎中分离得到两个新的降解环阿屯三萜类化合物,命名为 buboditones A、B(1、2),以及十个已知的生物碱:环布福维啶(3)、-二甲基环布福维辛(4)、环维罗布辛 C(5)、环维罗布辛 A(6)、环普罗托布辛 C(7)、环普罗托布辛 A(8)、环布福辛嗪(9)、环布福辛嗪 A(10)、布曲洛丁 B(11)、伊雷辛(12)。通过 1D 和 2D NMR 光谱方法(包括 HSQC、HMBC、H-H COSY、NOESY 以及 HRESIMS 光谱分析)阐明了化合物 1-12 的结构。