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硅表面-Si环结构形成的热力学分析。

Thermodynamical Analysis of the Formation of -Si Ring Structures on Silicon Surface.

作者信息

Jarutis Vygandas, Paipulas Domas, Jukna Vytautas

机构信息

Laser Research Center, Vilnius University, Sauletekio Avenue 10, LT-10223 Vilnius, Lithuania.

出版信息

Materials (Basel). 2023 Mar 9;16(6):2205. doi: 10.3390/ma16062205.

DOI:10.3390/ma16062205
PMID:36984084
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10058774/
Abstract

Superficial modifications on silicon wafers produced by single-shot focused femtosecond laser irradiation having a 1030 nm wavelength and 300 fs pulse duration were experimentally and theoretically analyzed. The laser fluence window when the amorphous silicon phase develops, resulting in a ring-like modification shape, was experimentally estimated to be between 0.26 J/cm2 and 0.40 J/cm2 and was independent of the silicon dopant type and laser focusing conditions; however, the window was narrower when compared to results reported for shorter pulse durations. In addition, we present a simplified numerical model that can explain and predict the formation of these patterns based on the caloric coefficients of silicon and the energy distribution of the deposited material.

摘要

对通过单次聚焦飞秒激光辐照产生的硅片表面改性进行了实验和理论分析,该激光波长为1030 nm,脉冲持续时间为300 fs。实验估计,当非晶硅相形成并产生环状改性形状时的激光能量密度窗口在0.26 J/cm²至0.40 J/cm²之间,且与硅掺杂剂类型和激光聚焦条件无关;然而,与报道的较短脉冲持续时间的结果相比,该窗口更窄。此外,我们提出了一个简化的数值模型,该模型可以基于硅的热系数和沉积材料的能量分布来解释和预测这些图案的形成。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5fe/10058774/2bbcfd28edb1/materials-16-02205-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5fe/10058774/99d908159e68/materials-16-02205-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5fe/10058774/7af8f103822b/materials-16-02205-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5fe/10058774/d9113d0860ae/materials-16-02205-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5fe/10058774/d78d2a4643a2/materials-16-02205-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5fe/10058774/2bbcfd28edb1/materials-16-02205-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5fe/10058774/99d908159e68/materials-16-02205-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5fe/10058774/7af8f103822b/materials-16-02205-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5fe/10058774/d9113d0860ae/materials-16-02205-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5fe/10058774/d78d2a4643a2/materials-16-02205-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b5fe/10058774/2bbcfd28edb1/materials-16-02205-g005.jpg

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本文引用的文献

1
Single Femtosecond Laser-Pulse-Induced Superficial Amorphization and Re-Crystallization of Silicon.单飞秒激光脉冲诱导的硅表面非晶化与再结晶
Materials (Basel). 2021 Mar 27;14(7):1651. doi: 10.3390/ma14071651.
2
Ultrafast laser processing of materials: from science to industry.材料的超快激光加工:从科学到工业
Light Sci Appl. 2016 Aug 12;5(8):e16133. doi: 10.1038/lsa.2016.133. eCollection 2016 Aug.
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Analysis of nascent silicon phase-change gratings induced by femtosecond laser irradiation in vacuum.真空中飞秒激光辐照诱导产生的初生硅相变光栅分析
Sci Rep. 2018 Aug 21;8(1):12498. doi: 10.1038/s41598-018-30269-0.
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Coherent scatter-controlled phase-change grating structures in silicon using femtosecond laser pulses.飞秒激光脉冲在硅中控制相干散射相变化光栅结构。
Sci Rep. 2017 Jul 4;7(1):4594. doi: 10.1038/s41598-017-04891-3.
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Femtosecond laser-controlled self-assembly of amorphous-crystalline nanogratings in silicon.飞秒激光控制硅中非晶-晶纳米光栅的自组装。
Nanotechnology. 2016 Jul 1;27(26):265602. doi: 10.1088/0957-4484/27/26/265602. Epub 2016 May 20.
6
Micro/nano scale amorphization of silicon by femtosecond laser irradiation.飞秒激光辐照硅的微纳尺度非晶化
Opt Express. 2009 Sep 14;17(19):16518-26. doi: 10.1364/OE.17.016518.
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Simple technique for measurements of pulsed Gaussian-beam spot sizes.测量脉冲高斯光束光斑尺寸的简单技术。
Opt Lett. 1982 May 1;7(5):196-8. doi: 10.1364/ol.7.000196.