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纯掺杂碳量子点作为荧光探针用于水族馆中酚类化合物和抗生素的检测。

Pure and doped carbon quantum dots as fluorescent probes for the detection of phenol compounds and antibiotics in aquariums.

机构信息

Faculty of Science, Benha University, Banha, Egypt.

Faculty of Science, Alexandria University, Alexandria, Egypt.

出版信息

Sci Rep. 2023 Aug 8;13(1):12863. doi: 10.1038/s41598-023-39490-y.

Abstract

The resulting antibiotic residue and organic chemicals from continuous climatic change, urbanization and increasing food demand have a detrimental impact on environmental and human health protection. So, we created a unique B, N-CQDs (Boron, Nitrogen doping carbon quantum dots) based fluorescent nanosensor to investigate novel sensing methodologies for the precise and concentrated identification of antibiotics and phenol derivatives substances to ensure that they are included in the permitted percentages. The as-prepared highly fluorescent B, N-CQDs had a limited range of sizes between 1 and 6 nm and average sizes of 2.5 nm in our study. The novel B, N-CQDs showed high sensitivity and selectivity for phenolic derivatives such as hydroquinone, resorcinol, and para aminophenol, as well as organic solvents such as hexane, with low detection limits of 0.05, 0.024, 0.032 and 0.013 µM respectively in an aqueous medium. The high fluorescence B, N-CQDs probes were examined using transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and UV/VIS spectroscopy. The outcomes were compared to carbon quantum dots (CQDs) previously generated from Urea.

摘要

不断变化的气候、城市化和日益增长的粮食需求所产生的抗生素残留和有机化学物质对环境保护和人类健康保护产生了不利影响。因此,我们创建了一种独特的基于 B、N-CQDs(硼、氮掺杂碳量子点)的荧光纳米传感器,以研究用于精确和集中识别抗生素和酚类衍生物物质的新型传感方法,以确保它们包含在允许的百分比内。在我们的研究中,所制备的高荧光 B、N-CQDs 的尺寸有限,在 1 到 6nm 之间,平均尺寸为 2.5nm。新型 B、N-CQDs 对酚类衍生物(如对苯二酚、间苯二酚和对氨基酚)以及有机溶剂(如己烷)表现出高灵敏度和选择性,在水溶液中的检测限分别低至 0.05、0.024、0.032 和 0.013µM。使用透射电子显微镜 (TEM)、X 射线衍射 (XRD)、傅里叶变换红外光谱 (FTIR) 和紫外/可见光谱对高荧光 B、N-CQDs 探针进行了检查。结果与先前从尿素中生成的碳量子点 (CQDs) 进行了比较。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4619/10409781/3dffa634cf21/41598_2023_39490_Fig1_HTML.jpg

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