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阐明高熵材料的四个核心效应。

Clarifying the four core effects of high-entropy materials.

作者信息

Hsu Wei-Lin, Tsai Che-Wei, Yeh An-Chou, Yeh Jien-Wei

机构信息

High Entropy Materials Center and Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu, Taiwan.

出版信息

Nat Rev Chem. 2024 Jun;8(6):471-485. doi: 10.1038/s41570-024-00602-5. Epub 2024 May 2.

Abstract

High-entropy materials emerged as a field of research in 2004, when the first research on high-entropy alloys was published. The scope was soon expanded from high-entropy alloys to medium-entropy alloys, as well as to ceramics, polymers and composite materials. A fundamental understanding on high-entropy materials was proposed in 2006 by the 'four core effects' - high-entropy, severe-lattice-distortion, sluggish-diffusion and cocktail effects - which are often used to describe and explain the mechanisms of various peculiar phenomena associated with high-entropy materials. Throughout the years, the effects have been examined rigorously, and their validity has been affirmed. This Perspective discusses the fundamental understanding of the four core effects in high-entropy materials and gives further insights to strengthen the understanding for these effects. All these clarifications are believed to be helpful in understanding low-to-high-entropy materials as well as to aid the design of materials when studying new compositions or pursuing their use in applications.

摘要

高熵材料作为一个研究领域于2004年出现,当时发表了第一篇关于高熵合金的研究。其范围很快从高熵合金扩展到中熵合金,以及陶瓷、聚合物和复合材料。2006年,通过“四个核心效应”——高熵、严重晶格畸变、扩散迟缓及混合效应——对高熵材料提出了基本认识,这些效应常被用于描述和解释与高熵材料相关的各种奇特现象的机制。多年来,这些效应已得到严格检验,其有效性也得到了肯定。本综述讨论了对高熵材料中四个核心效应的基本认识,并给出了进一步的见解以加强对这些效应的理解。相信所有这些阐释有助于理解低熵到高熵材料,以及在研究新成分或寻求其应用时辅助材料设计。

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