Abay Özlem, Ulusoy Murat, Uyar Esra, Gökmen Uğur, Bilge Ocak Sema
Graduate School of Natural and Applied Sciences, Department of Advanced Technologies, Gazi University, 06500 Ankara, Turkey.
Turkish Energy, Nuclear and Mineral Research Agency, 06980 Ankara, Turkey.
ACS Omega. 2024 May 20;9(22):23193-23201. doi: 10.1021/acsomega.3c08449. eCollection 2024 Jun 4.
This study investigates the beta irradiation's impact on the electrical features of interfacial nanostructures composed of poly(vinyl alcohol) (PVA) doped with graphene. The integration of graphene, a 2D carbon allotrope renowned for its exceptional electrical conductivity, into PVA nanostructures holds significant promise for advanced electronic applications. Beta irradiation, as a controlled method of introducing radiation, offers a unique avenue to modulate the properties of these nanostructures. Therefore, this study examines the Au/3% graphene(Gr)-doped PVA/n-type Si structure with and without beta (β) radiation. The effect of beta radiation on the electrical properties of the Au/3% graphene(Gr)-doped PVA/n-type Si structure has been researched by utilizing the current-voltage () data. The studied structures were exposed to a Sr β-ray source at room temperature to show the effect of beta radiation. The series resistance ( ), shunt resistance ( ), ideality factor (), barrier height (BH) (Φ), and saturation current ( ) were computed using the - data after Sr β-ray irradiation (0, 6, and 18 kGy) and before using the thermionic emission, Norde, and Cheung methods. The BH, ideality factor, and series resistance were calculated using the - data as follows: 0.888 eV, 3.21, and 5.25 kΩ for 0 kGy; 0.782 eV, 5.30, and 3.47 for 6 kGy; 0.782 eV, 5.46, and 2.63 kΩ for 18kGy. The BH, ideality factor, and series resistance were also calculated using the Cheng Methods, and the following results were found respectively: 7.22, 0.74, and 3.97 kΩ (Cheng I), and 3.22 kΩ (Cheng II) for 0 kGy; 5.14, 0.813, and 2.72 kΩ (Cheng I), and 2.14 kΩ (Cheng II) for 6 kGy; 6.78, 0.721, and 1.96 kΩ (Cheng I), 1.64 kΩ (Cheng II) for 18 kGy. The BH and series resistance were defined as 0.905 and 16.12 kΩ for 0 kGy, 0.859 and 5.31 kΩ for 6 kGy, and 0.792 and 2.49 kΩ for 18 kGy, respectively. Interface states density ( ) as a function of - was also attained by taking into account the voltage dependence of , Φ, and . Experimental results showed that the values of and increased with an increase in the β-ray radiation dose. On the other hand, the saturation current ( ), Φ, and values decreased with the increase in the β-ray radiation dose. The obtained results indicate a nuanced interplay between β irradiation dose and the nanostructure's overall electrical properties. Insights gained from this study contribute to the understanding of radiation-induced effects on graphene-doped polymer nanostructures, providing valuable information for optimizing their performance in electronic applications.
本研究调查了β辐射对由掺杂石墨烯的聚乙烯醇(PVA)组成的界面纳米结构电学特性的影响。石墨烯作为一种以其卓越的导电性而闻名的二维碳同素异形体,将其集成到PVA纳米结构中对先进电子应用具有重大前景。β辐射作为一种引入辐射的可控方法,为调节这些纳米结构的性质提供了一条独特途径。因此,本研究考察了有和没有β辐射的Au/3%石墨烯(Gr)掺杂PVA/n型硅结构。通过利用电流 - 电压(I - V)数据研究了β辐射对Au/3%石墨烯(Gr)掺杂PVA/n型硅结构电学性质的影响。在室温下将所研究的结构暴露于Srβ射线源以显示β辐射的效果。在Srβ射线辐照(0、6和18千戈瑞)之后以及使用热电子发射、诺德和张方法之前,利用I - V数据计算串联电阻(Rs)、并联电阻(Rsh)、理想因子(n)、势垒高度(BH)(ΦB)和饱和电流(Is)。利用I - V数据按如下方式计算BH、理想因子和串联电阻:对于0千戈瑞,分别为0.888电子伏特、3.21和5.25千欧;对于6千戈瑞,分别为0.782电子伏特、5.30和3.47;对于18千戈瑞,分别为0.782电子伏特、5.46和2.63千欧。还使用程氏方法计算BH、理想因子和串联电阻,分别得到以下结果:对于0千戈瑞,(程氏I)分别为7.22、0.74和3.97千欧,(程氏II)为3.22千欧;对于6千戈瑞,(程氏I)分别为5.14、0.813和2.72千欧,(程氏II)为2.14千欧;对于18千戈瑞,(程氏I)分别为6.78、0.721和1.96千欧,(程氏II)为1.64千欧。对于0千戈瑞,BH和串联电阻分别定义为0.905和16.12千欧;对于6千戈瑞,分别为0.859和