Lamon Denny, van der Donk Hidde A J, Verheijen Marcel A, Jansen Marvin M, Bakkers Erik P A M
Department of Applied Physics, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands.
Eurofins Materials Science Netherlands BV, 5656 AE Eindhoven, The Netherlands.
Nano Lett. 2025 Apr 9;25(14):5741-5746. doi: 10.1021/acs.nanolett.5c00267. Epub 2025 Mar 26.
Hexagonal SiGe, with its direct band gap, holds promising light-emission properties and potential for advanced optoelectronic applications. The growth of this material has been achieved as nanowires, within core-shell or multibranch trunk structures. However, core-shell designs are limited to radial growth, restricting the axial dimensional control, while multibranch structures lack growth precision, reducing their practical applicability. Here, we introduce a novel technique to grow hexagonal SiGe as single-branched nanowires, achieving unprecedented control over dimension and morphology. The branch diameter is precisely tuned by adjusting the trunk diameter, leveraging the use of the same Au catalyst particle throughout both trunk and branch growth. We investigate the growth rate and its diameter dependency within the Gibbs-Thomson framework, providing valuable insights into growth dynamics. This innovative method opens new opportunities for advanced studies on hexagonal SiGe, paving the way for developing next-generation quantum devices.
具有直接带隙的六方晶系硅锗具有良好的发光特性和在先进光电子应用中的潜力。这种材料已生长为纳米线,存在于核壳或多分支主干结构中。然而,核壳设计仅限于径向生长,限制了轴向尺寸控制,而多分支结构缺乏生长精度,降低了它们的实际适用性。在此,我们引入一种新技术来生长单分支纳米线形式的六方晶系硅锗,实现了对尺寸和形态前所未有的控制。通过调整主干直径精确调节分支直径,在主干和分支生长过程中利用相同的金催化剂颗粒。我们在吉布斯 - 汤姆逊框架内研究生长速率及其直径依赖性,为生长动力学提供了有价值的见解。这种创新方法为六方晶系硅锗的深入研究开辟了新机会,为开发下一代量子器件铺平了道路。