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纳米结构转换型阴极的最新进展：氟化物和硫化物

Recent Advances in Nanostructured Conversion-Type Cathodes: Fluorides and Sulfides.

作者信息

Islam Mobinul, Ahmed Md Shahriar, Yun Sua, Ali Basit, Kim Hae-Yong, Nam Kyung-Wan

机构信息

Department of Energy & Materials Engineering, Dongguk University, Seoul 04620, Republic of Korea.

Department of Advanced Battery Convergence Engineering, Dongguk University, Seoul 04620, Republic of Korea.

出版信息

Nanomaterials (Basel). 2025 Mar 8;15(6):420. doi: 10.3390/nano15060420.

DOI:10.3390/nano15060420
PMID:40137591
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11946122/
Abstract

This review paper explores the emerging field of conversion cathode materials, which hold significant promises for advancing the performance of lithium-ion (LIBs) and lithium-sulfur batteries (LSBs). Traditional cathode materials of LIBs, such as lithium cobalt oxide, have reached their limits in terms of energy density and capacity, driving the search for alternatives that can meet the increasing demands of modern technology, including electric vehicles and renewable energy systems. Conversion cathodes operate through a mechanism involving complete redox reactions, transforming into different phases, which enables the storage of more lithium ions and results in higher theoretical capacities compared to conventional intercalation materials. This study examines various conversion materials, including metal oxides, sulfides, and fluorides, highlighting their potential to significantly enhance energy density. Despite their advantages, conversion cathodes face numerous challenges, such as poor conductivity, significant volume changes during cycling, and issues with reversibility and stability. This review discusses current nanoengineering strategies employed to address these challenges, including nano structuring, composite formulation, and electrolyte optimization. By assessing recent research and developments in conversion cathode technology, this paper aims to provide a comprehensive overview of their potential to revolutionize lithium-ion batteries and contribute to the future of energy storage solutions.

摘要

这篇综述论文探讨了转换型阴极材料这一新兴领域，该领域对于提升锂离子电池（LIBs）和锂硫电池（LSBs）的性能有着重大前景。锂离子电池的传统阴极材料，如钴酸锂，在能量密度和容量方面已达到极限，这促使人们寻找能够满足现代技术（包括电动汽车和可再生能源系统）不断增长需求的替代材料。转换型阴极通过一种涉及完全氧化还原反应的机制运行，转变为不同的相，这使得其能够存储更多的锂离子，与传统的嵌入材料相比具有更高的理论容量。本研究考察了各种转换材料，包括金属氧化物、硫化物和氟化物，突出了它们显著提高能量密度的潜力。尽管具有优势，但转换型阴极面临诸多挑战，如导电性差、循环过程中体积变化大以及可逆性和稳定性问题。本综述讨论了当前用于应对这些挑战的纳米工程策略，包括纳米结构化、复合配方和电解质优化。通过评估转换型阴极技术的最新研究和进展，本文旨在全面概述它们在革新锂离子电池以及推动储能解决方案未来发展方面的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/3974183595ac/nanomaterials-15-00420-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/0b16212c0688/nanomaterials-15-00420-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/a97d61e009ad/nanomaterials-15-00420-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/6f8821479458/nanomaterials-15-00420-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/37bcc34ddfd9/nanomaterials-15-00420-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/30874cb745b1/nanomaterials-15-00420-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/dc456fecc0ac/nanomaterials-15-00420-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/16ec92e5f113/nanomaterials-15-00420-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/e73836daad66/nanomaterials-15-00420-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/5963389ec073/nanomaterials-15-00420-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/f43ec4e62ac3/nanomaterials-15-00420-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/da44ae0b2af8/nanomaterials-15-00420-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/3ac22fced940/nanomaterials-15-00420-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/d71886107298/nanomaterials-15-00420-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/658f6ca4ada8/nanomaterials-15-00420-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/3974183595ac/nanomaterials-15-00420-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/0b16212c0688/nanomaterials-15-00420-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/a97d61e009ad/nanomaterials-15-00420-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/6f8821479458/nanomaterials-15-00420-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/37bcc34ddfd9/nanomaterials-15-00420-sch002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/30874cb745b1/nanomaterials-15-00420-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/dc456fecc0ac/nanomaterials-15-00420-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/16ec92e5f113/nanomaterials-15-00420-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/e73836daad66/nanomaterials-15-00420-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/5963389ec073/nanomaterials-15-00420-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/f43ec4e62ac3/nanomaterials-15-00420-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/da44ae0b2af8/nanomaterials-15-00420-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/3ac22fced940/nanomaterials-15-00420-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/d71886107298/nanomaterials-15-00420-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/658f6ca4ada8/nanomaterials-15-00420-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1544/11946122/3974183595ac/nanomaterials-15-00420-g013.jpg

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