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通过成分依赖的铪锆氧化物超晶格实现的超高介电常数介质,用于具有NH等离子体优化界面的硅纳米片全栅场效应晶体管。

Super High-k Dielectric via Composition-Dependent Hafnium Zirconium Oxide Superlattice for Si Nanosheet Gate-All-Around Field-Effect Transistors with NH Plasma-Optimized Interfaces.

作者信息

Yao Yi-Ju, Fu Yu-Min, Chen Yu-Hung, Wei Chen-You, Huang Kai-Ting, Luo Guang-Li, Hou Fu-Ju, Lai Yu-Sheng, Wu Yung-Chun

机构信息

College of Semiconductor Research, National Tsing Hua University, Hsinchu 30013, Taiwan.

Department of Engineering and System Science, National Tsing Hua University, Hsinchu 30013, Taiwan.

出版信息

Materials (Basel). 2025 Apr 10;18(8):1740. doi: 10.3390/ma18081740.

DOI:10.3390/ma18081740
PMID:40333395
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12028565/
Abstract

This paper presents an advanced dielectric engineering approach utilizing a composition-dependent hafnium zirconium oxide (HfZrO) superlattice (SL) structure for Si nanosheet gate-all-around field-effect transistors (Si NSGAAFETs). The dielectric (DE) properties of solid solution (SS) and SL HfZrO capacitors were systematically characterized through capacitance-voltage (C-V) and polarization-voltage (P-V) measurements under varying annealing conditions. A high dielectric constant (k-value) of 59 was achieved in SL-HfZrO, leading to a substantial reduction in equivalent oxide thickness (EOT). Furthermore, the SL-HfZrO dielectric was integrated into Si NSGAAFETs, with the interfacial layer (IL) further optimized via NH plasma treatment. The resulting devices exhibited superior electrical performance, including an enhanced ON-OFF current ratio (I/I) reaching 10, an increased drive current, and significantly reduced gate leakage. These results highlight the potential of SL-HfZrO as a high-k dielectric solution for overcoming EOT scaling challenges in advanced CMOS technology and enabling further innovation in next-generation logic applications.

摘要

本文提出了一种先进的介电工程方法,该方法利用成分依赖的铪锆氧化物(HfZrO)超晶格(SL)结构来制备硅纳米片全栅场效应晶体管(Si NSGAAFETs)。通过在不同退火条件下进行电容-电压(C-V)和极化-电压(P-V)测量,系统地表征了固溶体(SS)和SL HfZrO电容器的介电(DE)特性。在SL-HfZrO中实现了59的高介电常数(k值),从而使等效氧化层厚度(EOT)大幅降低。此外,将SL-HfZrO电介质集成到Si NSGAAFETs中,并通过NH等离子体处理进一步优化界面层(IL)。所得器件表现出优异的电学性能,包括增强的开/关电流比(I/I)达到10、驱动电流增加以及栅极泄漏显著降低。这些结果突出了SL-HfZrO作为一种高k电介质解决方案的潜力,可用于克服先进CMOS技术中的EOT缩放挑战,并推动下一代逻辑应用的进一步创新。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75a/12028565/876bb3266449/materials-18-01740-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75a/12028565/601164e2cbc8/materials-18-01740-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75a/12028565/44712ae27b58/materials-18-01740-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75a/12028565/2a4b9c92f4f3/materials-18-01740-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75a/12028565/9cf3b7068997/materials-18-01740-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75a/12028565/3781d94c7bc3/materials-18-01740-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75a/12028565/8d160f1ca826/materials-18-01740-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75a/12028565/876bb3266449/materials-18-01740-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75a/12028565/601164e2cbc8/materials-18-01740-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75a/12028565/44712ae27b58/materials-18-01740-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75a/12028565/2a4b9c92f4f3/materials-18-01740-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75a/12028565/9cf3b7068997/materials-18-01740-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75a/12028565/3781d94c7bc3/materials-18-01740-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75a/12028565/8d160f1ca826/materials-18-01740-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e75a/12028565/876bb3266449/materials-18-01740-g007.jpg

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本文引用的文献

1
Ultrathin ferroic HfO-ZrO superlattice gate stack for advanced transistors.用于先进晶体管的超晶格铁电 HfO-ZrO 栅堆叠
Nature. 2022 Apr;604(7904):65-71. doi: 10.1038/s41586-022-04425-6. Epub 2022 Apr 6.
2
Fluorite-structure antiferroelectrics.萤石结构反铁电体。
Rep Prog Phys. 2019 Dec;82(12):124502. doi: 10.1088/1361-6633/ab49d6. Epub 2019 Oct 1.
3
Ultimate Scaling of High-κ Gate Dielectrics: Higher-κ or Interfacial Layer Scavenging?高κ栅介质的极限缩放:更高κ还是界面层清除?
Materials (Basel). 2012 Mar 14;5(3):478-500. doi: 10.3390/ma5030478.
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Ferroelectricity in Simple Binary ZrO2 and HfO2.简单二元 ZrO2 和 HfO2 中的铁电性。
Nano Lett. 2012 Aug 8;12(8):4318-23. doi: 10.1021/nl302049k. Epub 2012 Jul 23.