INTRODUCTION: Recent advancements in augmented reality (AR) technology have opened up potential applications across various industries. In this study, we assess the effectiveness of psychomotor learning in AR compared to video-based training methods. METHODS: Thirty-three participants (17 males) trained on four selection-based AR interactions by either watching a video or engaging in hands-on practice. Both groups were evaluated by executing these learned interactions in AR. RESULTS: The AR group reported a higher subjective workload during training but showed significantly faster completion times during evaluation. We analyzed brain activation and functional connectivity using functional near-infrared spectroscopy during the evaluation phase. Our findings indicate that participants who trained in AR displayed more efficient brain networks, suggesting improved neural efficiency. DISCUSSION: Differences in sex-related activation and connectivity hint at varying neural strategies used during motor learning in AR. Future studies should investigate how demographic factors might influence performance and user experience in AR-based training programs.