Song Ye, Zhu Wenkai, Wang Chaohai, Li Zequn, Xin Ruiqi, Wu Dujuan, Ma Xiaofan, Wang Hanwei, Wang Xiangyu, Li Song, Kim Jeonghun, Sun Qingfeng, Kim Minjun, Yamauchi Yusuke
College of Chemistry and Materials Engineering, Zhejiang A&F University, Hangzhou, 311300, China.
Henan Key Laboratory of Water Pollution Control and Rehabilitation Technology, Henan International Joint Laboratory for Green Low Carbon Water Treatment Technology and Water Resources Utilization, School of Municipal and Environmental Engineering, Henan University of Urban Construction, Pingdingshan, 467036, China.
Adv Mater. 2025 Oct;37(39):e2504364. doi: 10.1002/adma.202504364. Epub 2025 Jul 11.
Metal-organic frameworks (MOFs) are widely used in environmental remediation due to their unique properties. However, their practical applications are significantly limited by its powder crystal form. To address these limitations, MOFs can be integrated with abundant and sustainable biomass-derived nanocellulose (NC) to construct processable macroscopic architectures. Herein, this review discusses recent advances in the preparation of multi-dimensional macroscopic materials from MOFs-NC and their applications in environmental remediation, including dye adsorption and degradation, pharmaceutical removal, heavy metal ion capture, adsorption and degradation of volatile organic compounds (VOCs), CO capture and separation, particulate matter (PM) separation, and others. A summary of two commonly used strategies for preparing MOFs-NC composites proposes a valuable insight on how processable macroscopic architectures can be effectively achieved. Furthermore, this review provides an overview of the structure-property-function relationship between multi-dimensional MOFs-NC composites and highlights their versatile applications in the remediation of polluted environments. The mechanisms, challenges, and future prospects of the material in removing environmental pollutants are also present in detail. This review aims to guide researchers in designing high-performance, multi-functional, sustainable, and scalable MOFs-NC composites for future environmental remediation.
金属有机框架材料（MOFs）因其独特的性质而被广泛应用于环境修复领域。然而，其粉末晶体形态严重限制了它们的实际应用。为了解决这些限制，MOFs可以与丰富且可持续的生物质衍生纳米纤维素（NC）结合，构建可加工的宏观结构。在此，本综述讨论了由MOFs-NC制备多维宏观材料的最新进展及其在环境修复中的应用，包括染料吸附与降解、药物去除、重金属离子捕获、挥发性有机化合物（VOCs）的吸附与降解、CO捕获与分离、颗粒物（PM）分离等。对制备MOFs-NC复合材料的两种常用策略的总结，为如何有效实现可加工宏观结构提供了有价值的见解。此外，本综述概述了多维MOFs-NC复合材料的结构-性能-功能关系，并突出了它们在污染环境修复中的广泛应用。还详细介绍了该材料去除环境污染物的机制、挑战和未来前景。本综述旨在指导研究人员设计用于未来环境修复的高性能、多功能、可持续且可扩展的MOFs-NC复合材料。
