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1
The identification of the weak oestrogen equol [7-hydroxy-3-(4'-hydroxyphenyl)chroman] in human urine.人尿中弱雌激素雌马酚[7-羟基-3-(4'-羟基苯基)苯并二氢吡喃]的鉴定。
Biochem J. 1982 Feb 1;201(2):353-7. doi: 10.1042/bj2010353.
2
Soya--a dietary source of the non-steroidal oestrogen equol in man and animals.大豆——人和动物非甾体雌激素雌马酚的膳食来源。
J Endocrinol. 1984 Jul;102(1):49-56. doi: 10.1677/joe.0.1020049.
3
Identification of the phyto-oestrogen 3',7-dihydroxyisoflavan, an isomer of equol, in human urine and cow's milk.在人尿液和牛奶中鉴定出植物雌激素3',7-二羟基异黄酮，即雌马酚的一种异构体。
Biomed Environ Mass Spectrom. 1988 Jul;17(1):1-6. doi: 10.1002/bms.1200170104.
4
Identification of the isoflavonic phytoestrogen daidzein in human urine.人体尿液中异黄酮类植物雌激素黄豆苷元的鉴定。
Clin Chim Acta. 1984 Jan 31;136(2-3):165-72. doi: 10.1016/0009-8981(84)90288-2.
5
Equol and other compounds from bovine urine as monoamine oxidase inhibitors.来自牛尿液的雌马酚及其他化合物作为单胺氧化酶抑制剂
J Neural Transm. 1986;65(2):147-50. doi: 10.1007/BF01256490.
6
Identification of a non-steroidal estrogen, equol, in the urine of pregnant macaques: correlation with steroidal estrogen excretion.在怀孕猕猴尿液中鉴定出一种非甾体雌激素——雌马酚：与甾体雌激素排泄的相关性。
J Steroid Biochem. 1984 Apr;20(4A):869-76. doi: 10.1016/0022-4731(84)90398-4.
7
Excretion of the lignans enterolactone and enterodiol and of equol in omnivorous and vegetarian postmenopausal women and in women with breast cancer.杂食和素食绝经后女性以及乳腺癌女性中木脂素肠内酯、肠二醇和雌马酚的排泄情况。
Lancet. 1982 Dec 11;2(8311):1295-9. doi: 10.1016/s0140-6736(82)91507-0.
8
Characterization of the estrogenic properties of a nonsteroidal estrogen, equol, extracted from urine of pregnant macaques.
Biol Reprod. 1984 Nov;31(4):705-13. doi: 10.1095/biolreprod31.4.705.
9
Isotope dilution gas chromatographic-mass spectrometric method for the determination of lignans and isoflavonoids in human urine, including identification of genistein.用于测定人尿中木脂素和异黄酮（包括染料木黄酮鉴定）的同位素稀释气相色谱-质谱法
Clin Chim Acta. 1991 Jul 15;199(3):263-78. doi: 10.1016/0009-8981(91)90120-2.
10
Equol: a contributor to enigmatic immunoassay measurements of estrogen.雌马酚：雌激素神秘免疫测定结果的影响因素
Steroids. 1985 Jul;46(1):587-608. doi: 10.1016/0039-128x(85)90024-8.

引用本文的文献

1
Perspective: Isoflavones-Intriguing Molecules but Much Remains to Be Learned about These Soybean Constituents.观点：异黄酮——有趣的分子，但关于这些大豆成分仍有许多有待了解之处。
Adv Nutr. 2025 May;16(5):100418. doi: 10.1016/j.advnut.2025.100418. Epub 2025 Mar 27.
2
Advances in the Metabolic Mechanism and Functional Characteristics of Equol.雌马酚的代谢机制及功能特性研究进展
Foods. 2023 Jun 10;12(12):2334. doi: 10.3390/foods12122334.
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Tanshinone-I for the treatment of uterine fibroids: Molecular docking, simulation, and density functional theory investigations.丹参酮-I用于治疗子宫肌瘤：分子对接、模拟及密度泛函理论研究
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The role of isoflavones in augmenting the effects of radiotherapy.异黄酮在增强放射治疗效果中的作用。
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5
Dietary Isoflavone Aglycons from Soy Germ Pasta Improves Reproductive Performance of Aging Hens and Lowers Cholesterol Levels of Egg Yolk.大豆胚芽面食中的膳食异黄酮苷元可改善老龄母鸡的繁殖性能并降低蛋黄胆固醇水平。
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6
Soy and Frequent Dairy Consumption with Subsequent Equol Production Reveals Decreased Gut Health in a Cohort of Healthy Puerto Rican Women.大豆和频繁的乳制品摄入及其后续的大豆苷元生成，揭示了健康波多黎各女性队列的肠道健康状况下降。
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The Antioxidant Role of Soy and Soy Foods in Human Health.大豆及豆制品在人类健康中的抗氧化作用。
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8
Identification of equol-7-glucuronide-4'-sulfate, monoglucuronides and monosulfates in human plasma of 2 equol producers after administration of by LC-ESI-MS.采用 LC-ESI-MS 法鉴定 2 名大豆异黄酮代谢产物型人群口服后血浆中黄豆黄素-7-葡糖苷酸-4′-硫酸盐、单葡糖苷酸和单硫酸盐。
Pharmacol Res Perspect. 2019 May 9;7(3):e00478. doi: 10.1002/prp2.478. eCollection 2019 Jun.
9
Isoflavones.异黄酮。
Molecules. 2019 Mar 19;24(6):1076. doi: 10.3390/molecules24061076.
10
Effect of S-equol and Soy Isoflavones on Heart and Brain.S-雌马酚和大豆异黄酮对心脏和大脑的影响。
Curr Cardiol Rev. 2019;15(2):114-135. doi: 10.2174/1573403X15666181205104717.

本文引用的文献

1
Equol, a new inactive phenol isolated from the ketohydroxyoestrin fraction of mares' urine.雌马酚，一种从母马尿液的酮羟基雌激素部分分离出的新的非活性酚类物质。
Biochem J. 1932;26(4):1227-32. doi: 10.1042/bj0261227.
2
Estrogens and related substances in plants.
Vitam Horm. 1954;12:207-33. doi: 10.1016/s0083-6729(08)61013-4.
3
Identification of equol in the urine of the domestic fowl.
Biochim Biophys Acta. 1961 Oct 28;53:403-4. doi: 10.1016/0006-3002(61)90452-8.
4
Steroids and other lipids of pregnant cow's urine.
J Endocrinol. 1959 Jan;18(1):32-45. doi: 10.1677/joe.0.0180032.
5
Steroids and other lipids of pregnant goat's urine.怀孕山羊尿液中的类固醇及其他脂质。
Biochem J. 1957 May;66(1):92-101. doi: 10.1042/bj0660092.
6
Effect of equol on oestrogen receptors and on synthesis of DNA and protein in the immature rat uterus.雌马酚对未成熟大鼠子宫雌激素受体及DNA和蛋白质合成的影响。
J Endocrinol. 1980 May;85(2):291-7. doi: 10.1677/joe.0.0850291.
7
The definitive identification of the lignans trans-2,3-bis(3-hydroxybenzyl)-gamma-butyrolactone and 2,3-bis(3-hydroxybenzyl)butane-1,4-diol in human and animal urine.在人和动物尿液中对木脂素反式-2,3-双(3-羟基苄基)-γ-丁内酯和2,3-双(3-羟基苄基)丁烷-1,4-二醇的确证鉴定。
Biochem J. 1981 Aug 1;197(2):447-58. doi: 10.1042/bj1970447.
8
The excretion of lignans in rats -- evidence for an intestinal bacterial source for this new group of compounds.
FEBS Lett. 1981 Jan 26;123(2):337-42. doi: 10.1016/0014-5793(81)80322-5.
9
Conjugation of lignans in human urine.
FEBS Lett. 1980 Dec 15;122(1):49-53. doi: 10.1016/0014-5793(80)80399-1.
10
Lignans in man and in animal species.
Nature. 1980 Oct 23;287(5784):740-2. doi: 10.1038/287740a0.

人尿中弱雌激素雌马酚[7-羟基-3-(4'-羟基苯基)苯并二氢吡喃]的鉴定。

The identification of the weak oestrogen equol [7-hydroxy-3-(4'-hydroxyphenyl)chroman] in human urine.

作者信息

Axelson M, Kirk D N, Farrant R D, Cooley G, Lawson A M, Setchell K D

出版信息

Biochem J. 1982 Feb 1;201(2):353-7. doi: 10.1042/bj2010353.

DOI:10.1042/bj2010353
PMID:7082293
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC1163650/
Abstract

The identification (by gas chromatography-mass spectrometry and n.m.r.) for the first time of the weak oestrogen equol [7-hydroxy-3-(4'-hydroxyphenyl)chroman] in human urine is described. Preliminary results of its quantitative excretion in urine are reported and the potential significance of the occurrence of this compound is discussed.

摘要

首次描述了通过气相色谱 - 质谱联用和核磁共振在人尿中鉴定出弱雌激素雌马酚[7 - 羟基 - 3 - (4'- 羟基苯基)苯并二氢吡喃]。报告了其在尿液中定量排泄的初步结果，并讨论了该化合物存在的潜在意义。