Melville C R, Gould S J
Department of Chemistry, Oregon State University, Corvallis 97331-4003.
J Nat Prod. 1994 May;57(5):597-601. doi: 10.1021/np50107a005.
Murayalactone, 6, has been isolated from Streptomyces murayamaensis, and its structure assigned with the use of inverse nmr spectroscopy. This constitutes the first occurrence of a dibenzo-alpha-pyrone in a Streptomyces species, and the first biogenesis of this ring system from a decaketide.
村山内酯(6)已从村山链霉菌中分离出来,并通过逆核磁共振光谱确定了其结构。这是二苯并-α-吡喃酮首次在链霉菌属物种中出现,也是该环系首次由十酮肽生物合成。