动力学共振拉曼光谱：细菌视紫红质席夫碱的去质子化动力学
Kinetic resonance Raman spectroscopy: dynamics of deprotonation of the Schiff base of bacteriorhodopsin.
作者信息
Marcus M A, Lewis A
出版信息
Science. 1977 Mar 25;195(4284):1328-30. doi: 10.1126/science.841330.
PMID:841330
Abstract
We have developed a kinetic technique, combining resonance Raman spectroscopy and variable-speed continuous flow methods, to study molecular dynamics of isolated sites in macromolecules. Kinetic resonance Raman spectra of the retinylidence chromophore of bacteriorhodopsin have been obtained and the dynamics of the deprotonation of the Schiff base linkage is discussed.
摘要
我们开发了一种动力学技术，将共振拉曼光谱与变速连续流动方法相结合，以研究大分子中孤立位点的分子动力学。已获得细菌视紫红质视黄醛发色团的动力学共振拉曼光谱，并讨论了席夫碱键去质子化的动力学。
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