Vitali Matteo, Ensabella Francesca, Stella Daniela, Guidotti Maurizio
Department of Sciences of Public Health G. Sanarelli, University of Rome La Sapienza, Piazzale Aldo Moro, 5, 00185 Roma, Italy.
Ind Health. 2006 Apr;44(2):310-7. doi: 10.2486/indhealth.44.310.
Car repair painters usually experience long-term exposure to many different solvents. In Italy, the greater part of car painting shops are "handicraft", i.e. 2-5 workers and small premises. Usually workers do not have specific duties, but everyone takes part in all different operations. Moreover, working time is not standardized but varies according to the workload, working methods tend to be traditional, and compliance to individual protection devices is poor. We have hence assessed, on a sample of 8 italian handicraft car painting shops, the exposure levels to solvents, implementing three classic exposure monitoring methods: environmental sampling with charcoal tubes, personal sampling with diffusive charcoal samplers, and urinary determination of unmetabolised solvents. A simple regression analysis was performed to evaluate relationships between the three series of data. The solvents analysed were toluene, ethylbenzene, 1, 2-dichloropropane, n-butylacetate, n-amylacetate, xylene isomers, ethylacetate, and benzene. Benzene was included due to several factors, among others its presence (1% v/v) in the italian unleaded gasoline. Benzene was found in all shops, at levels around or higher than the 8-h time-weighted average limit (8-h TLV-TWA). Other solvents were found in the different shops at various levels, 10(-2) - 10(-1) times the 8-h TLV-TWA. Air concentrations of toluene, n-butylacetate, xylenes, and benzene were positively correlated with urinary levels of the parent compounds, while a negative correlation was found for ethylbenzene. The health implications of workers' exposure level was briefly discussed.
汽车修理喷漆工通常长期接触多种不同的溶剂。在意大利,大部分汽车喷漆店都是“手工作坊式”的,即有2至5名工人且店面较小。通常工人没有明确的分工,而是每个人都参与所有不同的操作。此外,工作时间不规范,而是根据工作量有所不同,工作方法往往较为传统,对个人防护设备的依从性较差。因此,我们在8家意大利手工作坊式汽车喷漆店的样本中,采用三种经典的接触监测方法评估了溶剂接触水平:用活性炭管进行环境采样、用扩散式活性炭采样器进行个人采样以及对未代谢溶剂进行尿液测定。进行了简单的回归分析以评估这三组数据之间的关系。所分析的溶剂有甲苯、乙苯、1,2 - 二氯丙烷、乙酸正丁酯、乙酸正戊酯、二甲苯异构体、乙酸乙酯和苯。由于多种因素将苯纳入分析,其中包括苯在意大利无铅汽油中的存在(体积分数1%)。在所有店铺中均检测到苯,其浓度达到或高于8小时时间加权平均限值(8 - h TLV - TWA)。在不同店铺中还检测到其他溶剂,浓度为8小时TLV - TWA的10⁻²至10⁻¹倍。甲苯、乙酸正丁酯、二甲苯和苯的空气浓度与母体化合物的尿液水平呈正相关,而乙苯则呈负相关。简要讨论了工人接触水平对健康的影响。