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采用 ICP-OES 法测定土耳其穆拉地区热电厂周围蘑菇样品中的汞、镉、铅、锌、硒和铁。

Determination of mercury, cadmium, lead, zinc, selenium and iron by ICP-OES in mushroom samples from around thermal power plant in Muğla, Turkey.

机构信息

Department of Chemistry, Faculty of Science, Muğla University, Turkey.

出版信息

Bull Environ Contam Toxicol. 2011 Sep;87(3):276-81. doi: 10.1007/s00128-011-0357-1. Epub 2011 Jul 7.

DOI:10.1007/s00128-011-0357-1
PMID:21735274
Abstract

Scleroderma verrucosum, Stropharia coronilla, Lactarius deterrimus, Chroogomphus rutilus, Russula delica, Laccaria laccata, Clitocybe odora var. alba, Lyophyllum decastes, Coprinus comatus, Helvella leucomelaena, Melanoleuca cognata, Melanoleuca cognata, Paxina acetabulum, Clitocybe vermicularis, Sarcosphaera crassa, Rhizopogon roseolu and Thelephora caryophyllea were collected from different localities in Muğla-Yatağan region of Turkey. Their trace metals concentrations were determined by ICPOES after microwave digestion. The results were 0.37 ± 0.01-5.28 ± 0.21 for cadmium, 467 ± 19-3,280 ± 131 for iron, 0.69 ± 0.03-9.15 ± 0.37 for lead, 18.70 ± 0.75-67.10 ± 2.68 for selenium, 75 ± 3-213 ± 8 for zinc and 0.15 ± 0.01-0.55 ± 0.01 for mercury (as μg/g). The detection limits for ICPOES were found as 0.25 for Cadmium, 0.2 for iron, 0.1 for lead, 0.5 for selenium, 0.2 for zinc and 0.03 for mercury (as mg L(-1)). The Relatively Standard Deviations (R.S.D.) were found below 4.0%. The accuracy of procedure was confirmed by certified reference material.

摘要

硬皮地星、冠状枝珊瑚菌、毒红菇、红绒盖牛肝菌、美味牛肝菌、乳菇、白边黄漏斗伞、漏斗状蜡伞、绒边乳菇、胶陀螺、小皮伞、纤柄白环蘑、大球盖菇、玫瑰红马勃、小地星、卷边网褶菌和裂皮鹅膏菌被采集自土耳其穆拉-亚塔伊地区的不同地点。它们的痕量金属浓度通过微波消解后用 ICPOES 进行了测定。结果为:镉 0.37 ± 0.01-5.28 ± 0.21,铁 467 ± 19-3,280 ± 131,铅 0.69 ± 0.03-9.15 ± 0.37,硒 18.70 ± 0.75-67.10 ± 2.68,锌 75 ± 3-213 ± 8,汞 0.15 ± 0.01-0.55 ± 0.01(均以 μg/g 计)。ICP-OES 的检测限被发现为:镉 0.25,铁 0.2,铅 0.1,硒 0.5,锌 0.2,汞 0.03(均以 mg/L 计)。相对标准偏差(R.S.D.)低于 4.0%。通过认证参考物质确认了该程序的准确性。

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