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Combining a Nitrogenase Scaffold and a Synthetic Compound into an Artificial Enzyme.
Angew Chem Int Ed Engl. 2015 Nov 16;54(47):14022-5. doi: 10.1002/anie.201507646. Epub 2015 Oct 16.
2
Reduction of C Substrates to Hydrocarbons by the Homometallic Precursor and Synthetic Mimic of the Nitrogenase Cofactor.
J Am Chem Soc. 2017 Jan 18;139(2):603-606. doi: 10.1021/jacs.6b11633. Epub 2017 Jan 6.
3
Incorporation of an Asymmetric Mo-Fe-S Cluster as an Artificial Cofactor into Nitrogenase.
Chembiochem. 2022 Oct 6;23(19):e202200384. doi: 10.1002/cbic.202200384. Epub 2022 Aug 25.
4
Assembly scaffold NifEN: A structural and functional homolog of the nitrogenase catalytic component.
Proc Natl Acad Sci U S A. 2016 Aug 23;113(34):9504-8. doi: 10.1073/pnas.1609574113. Epub 2016 Aug 9.
5
Widening the Product Profile of Carbon Dioxide Reduction by Vanadium Nitrogenase.
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6
Insights into hydrocarbon formation by nitrogenase cofactor homologs.
mBio. 2015 Apr 14;6(2):e00307-15. doi: 10.1128/mBio.00307-15.
7
Chemical Synthesis of an Asymmetric Mimic of the Nitrogenase Active Site.
Methods Mol Biol. 2019;1876:229-244. doi: 10.1007/978-1-4939-8864-8_15.
8
Cluster assembly in nitrogenase.
Essays Biochem. 2017 May 9;61(2):271-279. doi: 10.1042/EBC20160071.
9
Nitrogenase Cofactor Assembly: An Elemental Inventory.
Acc Chem Res. 2017 Nov 21;50(11):2834-2841. doi: 10.1021/acs.accounts.7b00417. Epub 2017 Oct 24.
10
Misconception of reductive elimination of H2, in the context of the mechanism of nitrogenase.
Dalton Trans. 2015 May 21;44(19):9027-37. doi: 10.1039/c5dt00771b.

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1
Prebiotic synthesis of the major classes of iron-sulfur clusters.
Chem Sci. 2025 Feb 11;16(11):4614-4624. doi: 10.1039/d5sc00524h. eCollection 2025 Mar 12.
2
Catalytic Reduction of Cyanide to Ammonia and Methane at a Mononuclear Fe Site.
J Am Chem Soc. 2024 Feb 28;146(8):5343-5354. doi: 10.1021/jacs.3c12395. Epub 2024 Feb 15.
3
Enzymatic Fischer-Tropsch-Type Reactions.
Chem Rev. 2023 May 10;123(9):5755-5797. doi: 10.1021/acs.chemrev.2c00612. Epub 2022 Dec 21.
4
Incorporation of an Asymmetric Mo-Fe-S Cluster as an Artificial Cofactor into Nitrogenase.
Chembiochem. 2022 Oct 6;23(19):e202200384. doi: 10.1002/cbic.202200384. Epub 2022 Aug 25.
5
Reconstruction of Nitrogenase Predecessors Suggests Origin from Maturase-Like Proteins.
Genome Biol Evol. 2022 Mar 2;14(3). doi: 10.1093/gbe/evac031.
6
Repurposing metalloproteins as mimics of natural metalloenzymes for small-molecule activation.
J Inorg Biochem. 2021 Jun;219:111430. doi: 10.1016/j.jinorgbio.2021.111430. Epub 2021 Mar 18.
7
From protein engineering to artificial enzymes - biological and biomimetic approaches towards sustainable hydrogen production.
Sustain Energy Fuels. 2018 Apr 1;2(4):724-750. doi: 10.1039/c7se00582b. Epub 2018 Feb 6.
8
Rational Design of Artificial Metalloproteins and Metalloenzymes with Metal Clusters.
Molecules. 2019 Jul 29;24(15):2743. doi: 10.3390/molecules24152743.
9
Tracing the 'ninth sulfur' of the nitrogenase cofactor via a semi-synthetic approach.
Nat Chem. 2018 May;10(5):568-572. doi: 10.1038/s41557-018-0029-4. Epub 2018 Apr 16.
10
Proton-Coupled Reduction of an Iron Cyanide Complex to Methane and Ammonia.
Angew Chem Int Ed Engl. 2016 Sep 26;55(40):12262-5. doi: 10.1002/anie.201606366. Epub 2016 Sep 8.

本文引用的文献

1
Catalytic reduction of CN-, CO, and CO2 by nitrogenase cofactors in lanthanide-driven reactions.
Angew Chem Int Ed Engl. 2015 Jan 19;54(4):1219-22. doi: 10.1002/anie.201410412. Epub 2014 Nov 24.
2
Ligand binding to the FeMo-cofactor: structures of CO-bound and reactivated nitrogenase.
Science. 2014 Sep 26;345(6204):1620-3. doi: 10.1126/science.1256679.
3
Differential reduction of CO₂ by molybdenum and vanadium nitrogenases.
Angew Chem Int Ed Engl. 2014 Oct 20;53(43):11543-6. doi: 10.1002/anie.201406863. Epub 2014 Sep 9.
4
Mechanism of nitrogen fixation by nitrogenase: the next stage.
Chem Rev. 2014 Apr 23;114(8):4041-62. doi: 10.1021/cr400641x. Epub 2014 Jan 27.
5
Developments in the biomimetic chemistry of cubane-type and higher nuclearity iron-sulfur clusters.
Chem Rev. 2014 Apr 9;114(7):3579-600. doi: 10.1021/cr4004067. Epub 2014 Jan 13.
6
Biosynthesis of nitrogenase metalloclusters.
Chem Rev. 2014 Apr 23;114(8):4063-80. doi: 10.1021/cr400463x. Epub 2013 Dec 13.
7
Spontaneous activation of [FeFe]-hydrogenases by an inorganic [2Fe] active site mimic.
Nat Chem Biol. 2013 Oct;9(10):607-609. doi: 10.1038/nchembio.1311. Epub 2013 Aug 11.
8
Biomimetic assembly and activation of [FeFe]-hydrogenases.
Nature. 2013 Jul 4;499(7456):66-69. doi: 10.1038/nature12239. Epub 2013 Jun 26.
9
Radical SAM-dependent carbon insertion into the nitrogenase M-cluster.
Science. 2012 Sep 28;337(6102):1672-5. doi: 10.1126/science.1224603.
10
X-ray emission spectroscopy evidences a central carbon in the nitrogenase iron-molybdenum cofactor.
Science. 2011 Nov 18;334(6058):974-7. doi: 10.1126/science.1206445.

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