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对钛-6铝-4钒合金上微弧氧化涂层中所含锌和磷元素的研究。

Investigation of Zinc and Phosphorus Elements Incorporated into Micro-Arc Oxidation Coatings Developed on Ti-6Al-4V Alloys.

作者信息

Wang Yaping, Zeng Lilan, Zhang Honghua, Xiang Junhuai, Zhang Shufang, Chang Wenhui, Zhang Rongfa, Wang Qiao, Sheng Yang, Zhao Ying

机构信息

School of Materials and Electromechanics, Jiangxi Science and Technology Normal University, Nanchang 330013, China.

Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China.

出版信息

Materials (Basel). 2018 Feb 27;11(3):344. doi: 10.3390/ma11030344.

DOI:10.3390/ma11030344
PMID:29495479
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5872923/
Abstract

In order to clarify the mechanism that zinc and phosphorus elements entering the micro-arc oxidation (MAO) coatings developed on Ti-6Al-4V alloys, anodic coatings containing different zinc and phosphorus were fabricated using an orthogonal experiment of four factors with three levels in an electrolyte containing EDTA-ZnNa₂, KOH, and phytic acid. Surface morphology, element composition, chemical state and phase structure of MAO coatings were characterized by scanning electron microscope (SEM), energy dispersive X-ray spectrometer (EDS), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). The concentrations of zinc and phosphorus in the electrolyte were analyzed by an inductively coupled plasma optical emission spectrometry (ICP-OES). The results show that zinc and phosphorus elements in MAO coatings exist in the form of Zn₃(PO₄)₂. Phytic acid is the most important factor on both zinc and phosphorus contents of MAO coatings. With the increase of phytic acid concentration or the decrease of KOH concentration, the contents of zinc and phosphorus in MAO coatings present a similarly increasing tendency. Our results indicate that phosphorus takes part in coating formation mainly by diffusion, while zinc enters into MAO coatings with phosphorus from phytic acid.

摘要

为了阐明锌和磷元素进入在Ti-6Al-4V合金上制备的微弧氧化（MAO）涂层的机制，在含有EDTA-ZnNa₂、KOH和植酸的电解液中，采用四因素三水平的正交试验制备了含有不同锌和磷的阳极涂层。通过扫描电子显微镜（SEM）、能量色散X射线光谱仪（EDS）、X射线光电子能谱（XPS）和X射线衍射（XRD）对MAO涂层的表面形貌、元素组成、化学状态和相结构进行了表征。采用电感耦合等离子体发射光谱法（ICP-OES）分析了电解液中锌和磷的浓度。结果表明，MAO涂层中的锌和磷元素以Zn₃(PO₄)₂的形式存在。植酸是影响MAO涂层中锌和磷含量的最重要因素。随着植酸浓度的增加或KOH浓度的降低，MAO涂层中锌和磷的含量呈现出相似的增加趋势。我们的结果表明，磷主要通过扩散参与涂层形成，而锌则与来自植酸的磷一起进入MAO涂层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9df3/5872923/2ebe8807a757/materials-11-00344-g010.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9df3/5872923/dfd0b0c40341/materials-11-00344-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9df3/5872923/08ac7800c61f/materials-11-00344-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9df3/5872923/2ebe8807a757/materials-11-00344-g010.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9df3/5872923/ced622ebd88a/materials-11-00344-g002.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9df3/5872923/3868b3e160d9/materials-11-00344-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9df3/5872923/4d871e18d3d1/materials-11-00344-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9df3/5872923/31e24fe348a2/materials-11-00344-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9df3/5872923/dfd0b0c40341/materials-11-00344-g008.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9df3/5872923/2ebe8807a757/materials-11-00344-g010.jpg

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