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用于半导体基光电化学析氧的助催化剂的合理设计与构建：综述

Rational Design and Construction of Cocatalysts for Semiconductor-Based Photo-Electrochemical Oxygen Evolution: A Comprehensive Review.

作者信息

Xu Xiao-Ting, Pan Lun, Zhang Xiangwen, Wang Li, Zou Ji-Jun

机构信息

Key Laboratory for Green Chemical Technology of the Ministry of Education School of Chemical Engineering and Technology Tianjin University Tianjin 300072 China.

Collaborative Innovative Center of Chemical Science and Engineering (Tianjin) Tianjin 300072 China.

出版信息

Adv Sci (Weinh). 2018 Nov 19;6(2):1801505. doi: 10.1002/advs.201801505. eCollection 2019 Jan 23.

DOI:10.1002/advs.201801505
PMID:30693190
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6343073/
Abstract

Photo-electrochemical (PEC) water splitting, as an essential and indispensable research branch of solar energy applications, has achieved increasing attention in the past decades. Between the two photoelectrodes, the photoanodes for PEC water oxidation are mostly studied for the facile selection of n-type semiconductors. Initially, the efficiency of the PEC process is rather limited, which mainly results from the existing drawbacks of photoanodes such as instability and serious charge-carrier recombination. To improve PEC performances, researchers gradually focus on exploring many strategies, among which engineering photoelectrodes with suitable cocatalysts is one of the most feasible and promising methods to lower reaction obstacles and boost PEC water splitting ability. Here, the basic principles, modules of the PEC system, evaluation parameters in PEC water oxidation reactions occurring on the surface of photoanodes, and the basic functions of cocatalysts on the promotion of PEC performance are demonstrated. Then, the key progress of cocatalyst design and construction applied to photoanodes for PEC oxygen evolution is emphatically introduced and the influences of different kinds of water oxidation cocatalysts are elucidated in detail. Finally, the outlook of highly active cocatalysts for the photosynthesis process is also included.

摘要

光电化学（PEC）水分解作为太阳能应用中一个至关重要且不可或缺的研究分支，在过去几十年里受到了越来越多的关注。在两个光电极之间，用于PEC水氧化的光阳极大多针对易于选择的n型半导体进行研究。最初，PEC过程的效率相当有限，这主要是由于光阳极存在诸如不稳定性和严重的电荷载流子复合等缺点。为了提高PEC性能，研究人员逐渐专注于探索多种策略，其中用合适的助催化剂对光电极进行工程设计是降低反应障碍和提高PEC水分解能力的最可行且最有前景的方法之一。在此，阐述了PEC系统的基本原理、模块、光阳极表面发生的PEC水氧化反应中的评估参数以及助催化剂对促进PEC性能的基本作用。然后，着重介绍了应用于PEC析氧光阳极的助催化剂设计与构建的关键进展，并详细阐明了不同种类的水氧化助催化剂的影响。最后，还包括了对光合作用过程中高活性助催化剂的展望。

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