Department of Electrical and Computer Engineering, Duke University, Durham, NC 27708, USA.
Nanoscale. 2019 Aug 1;11(30):14294-14302. doi: 10.1039/c9nr03378e.
Room-temperature printing of conductive traces has the potential to facilitate the direct writing of electronic tattoos and other medical devices onto biological tissue, such as human skin. However, in order to achieve sufficient electrical performance, the vast majority of conductive inks require biologically harmful post-processing techniques. In addition, most printed conductive traces will degrade with bending stresses that occur from everyday movement. In this work, water-based inks consisting of high aspect ratio silver nanowires are shown to enable the printing of conductive traces at low temperatures and without harmful post-processing. Moreover, the traces produced from these inks retain high electrical performance, even while undergoing up to 50% bending strain and cyclic bending strain over a thousand bending cycles. This ink has a rapid dry time of less than 2 minutes, which is imperative for applications requiring the direct writing of electronics on sensitive surfaces. Demonstrations of conductive traces printed onto soft, nonplanar materials, including an apple and a human finger, highlight the utility of these new silver nanowire inks. These mechanically robust films are ideally suited for printing directly on biological substrates and may find potential applications in the direct-write printing of electronic tattoos and other biomedical devices.
室温下打印导电迹线有可能实现电子纹身和其他医疗设备直接打印到生物组织(如人体皮肤)上。然而,为了实现足够的电气性能,绝大多数导电油墨需要使用对生物有害的后处理技术。此外,大多数打印的导电迹线会因日常运动产生的弯曲应力而退化。在这项工作中,展示了基于高纵横比银纳米线的水性油墨能够在低温下进行打印,且无需有害的后处理。此外,即使在经历高达 50%的弯曲应变和超过 1000 次弯曲循环的循环弯曲应变下,这些油墨产生的迹线仍保持着高的电性能。这种油墨的干燥时间快,不到 2 分钟,对于需要在敏感表面上直接写入电子器件的应用来说至关重要。在柔软、非平面材料(包括苹果和人的手指)上打印导电迹线的演示突出了这些新型银纳米线油墨的实用性。这些机械强度高的薄膜非常适合直接在生物衬底上打印,并且可能在电子纹身和其他生物医学设备的直接写入打印中有潜在的应用。