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镁合金 AZ31 阳极氧化工艺的调整用于可生物降解植入物。

Tuning of the Mg Alloy AZ31 Anodizing Process for Biodegradable Implants.

机构信息

Dipartimento di Ingegneria, Università degli Studi di Palermo, Viale delle Scienze, Palermo 90128, Italy.

Dipartimento di Scienze e Tecnologie Biologiche, Università degli Studi di Palermo, Chimiche e Farmaceutiche (STEBICEF), Viale delle Scienze, Palermo 90128, Italy.

出版信息

ACS Appl Mater Interfaces. 2021 Mar 24;13(11):12866-12876. doi: 10.1021/acsami.0c22933. Epub 2021 Mar 11.

DOI:10.1021/acsami.0c22933
PMID:33705091
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8041254/
Abstract

Coatings were grown on the AZ31 Mg alloy by a hard anodizing process in the hot glycerol phosphate-containing electrolyte. Anodizing conditions were optimized, maximizing corrosion resistance estimated by impedance measurements carried out in Hank's solution at 37 °C. A post anodizing annealing treatment (350 °C for 24 h) allowed us to further enhance the corrosion resistance of the coatings mainly containing magnesium phosphate according to energy-dispersive X-ray spectroscopy and Raman analyses. Gravimetric measurements revealed a hydrogen evolution rate within the limits acceptable for application of AZ31 in biomedical devices. tests demonstrated that the coatings are biocompatible with a preosteoblast cell line.

摘要

采用热甘油磷酸盐电解液中的硬质阳极氧化工艺在 AZ31 Mg 合金上生长涂层。优化了阳极氧化条件,通过在 37°C 的 Hank's 溶液中进行阻抗测量来最大限度地提高耐腐蚀性。后阳极氧化退火处理(350°C,24 h)使我们能够根据能谱和拉曼分析进一步提高主要含磷酸镁涂层的耐腐蚀性。重量测量表明氢的析出率在可接受的范围内,可用于 AZ31 在生物医学设备中的应用。细胞毒性测试表明,涂层与成骨前体细胞系具有生物相容性。

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