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更换旧的软垫家具后,灰尘中的阻燃剂浓度会发生变化吗?

Do flame retardant concentrations change in dust after older upholstered furniture is replaced?

作者信息

Rodgers Kathryn M, Bennett Deborah, Moran Rebecca, Knox Kristin, Stoiber Tasha, Gill Ranjit, Young Thomas M, Blum Arlene, Dodson Robin E

机构信息

Silent Spring Institute, 320 Nevada Street, Newton, MA 02460, United States.

University of California, Davis Department of Public Health Sciences, One Shields Ave, Davis, CA 95616, United States.

出版信息

Environ Int. 2021 Aug;153:106513. doi: 10.1016/j.envint.2021.106513. Epub 2021 Mar 23.

Abstract

Upholstered furniture has been a major source of chemical flame retardant (FR) exposures in US homes since the 1970s. FRs are a large group of chemicals, many of which are associated with adverse health effects, including cancer, reproductive toxicity, and neurotoxicity. California homes have some of the highest dust concentrations of FRs, due to Technical Bulletin 117 (TB117), California's outdated flammability standard for furniture foam that was generally followed across the US and Canada. In 2014, this standard was updated to a smolder standard for furniture fabric called TB117-2013, and it is no longer reliant on FRs. This update provided an opportunity to measure differences in FR dust levels in California homes before and after residents replaced older upholstered furniture, or its foam, with products that met the new standard and were expected to be FR-free. We collected dust from homes of participants who had plans to replace older upholstered furniture, or furniture foam, with FR-free options. We returned for follow-up dust collection six, 12, and 18 months following replacement. Concentrations of three polybrominated diphenyl ethers (PBDEs) (BDE-47, BDE-99, BDE-100), three chlorinated organophosphate ester FRs (tris(2-chloroethyl) phosphate (TCEP), tris(2-chloroisopropyl) phosphate (TCIPP), and tris(1,3-dichloroisopropyl) phosphate (TDCIPP)), and one aryl organophosphate ester FR triphenyl phosphate (TPHP), were widely detected in participant homes. All measured FRs decreased in nearly all homes after the older upholstered furniture was replaced. The decreases in FRs were significant in both homes that replaced entire pieces of furniture and those that replaced only the furniture foam. This study demonstrates that replacing older upholstered furniture or foam significantly reduces concentrations of a range of FRs in the home. Foam replacement offers a potentially more economic alternative that produces a lower volume of waste.

摘要

自20世纪70年代以来,软体家具一直是美国家庭接触化学阻燃剂(FR)的主要来源。阻燃剂是一大类化学物质,其中许多与不良健康影响有关,包括癌症、生殖毒性和神经毒性。由于技术公告117(TB117),加利福尼亚州家庭中的阻燃剂粉尘浓度在某些地区是最高的,TB117是加利福尼亚州过时的家具泡沫易燃性标准,美国和加拿大各地普遍遵循该标准。2014年,该标准更新为名为TB117 - 2013的家具织物闷烧标准,并且不再依赖阻燃剂。这一更新提供了一个机会,来测量加利福尼亚州居民用符合新标准且预计不含阻燃剂的产品替换旧软体家具或其泡沫前后,家庭中阻燃剂粉尘水平的差异。我们从计划用无阻燃剂产品替换旧软体家具或家具泡沫的参与者家中收集灰尘。替换后6个月、12个月和18个月,我们再次回访进行后续灰尘收集。在参与者家中广泛检测到三种多溴二苯醚(PBDEs)(BDE - 47、BDE - 99、BDE - 100)、三种氯化有机磷酸酯阻燃剂(磷酸三(2 - 氯乙基)酯(TCEP)、磷酸三(2 - 氯异丙基)酯(TCIPP)和磷酸三(1,3 - 二氯异丙基)酯(TDCIPP))以及一种芳基有机磷酸酯阻燃剂磷酸三苯酯(TPHP)。在替换旧软体家具后,几乎所有家庭中所有测量的阻燃剂含量都有所下降。在更换了整件家具的家庭和只更换了家具泡沫的家庭中,阻燃剂的下降都很显著。这项研究表明,更换旧软体家具或泡沫可显著降低家庭中一系列阻燃剂的浓度。更换泡沫提供了一种可能更经济的选择,产生的废物量也更少。

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