Ozkan Mihrimah, Nayak Saswat Priyadarshi, Ruiz Anthony D, Jiang Wenmei
Department of Electrical and Computer Engineering, University of California Riverside, Riverside, CA, USA.
Department of Chemistry, University of California Riverside, Riverside, CA, USA.
iScience. 2022 Feb 28;25(4):103990. doi: 10.1016/j.isci.2022.103990. eCollection 2022 Apr 15.
Climate change calls for adaptation of negative emission technologies such as direct air capture (DAC) of carbon dioxide (CO) to lower the global warming impacts of greenhouse gases. Recently, elevated global interests to the DAC technologies prompted implementation of new tax credits and new policies worldwide that motivated the existing DAC companies and prompted the startup boom. There are presently 19 DAC plants operating worldwide, capturing more than 0.01 Mt CO/year. DAC active plants capturing in average 10,000 tons of CO annually are still in their infancy and are expensive. DAC technologies still need to improve in three areas: 1) Contactor, 2) Sorbent, and 3) Regeneration to drive down the costs. Technology-based economic development in all three areas are required to achieve <$100/ton of CO which makes DAC economically viable. Current DAC cost is about 2-6 times higher than the desired cost and depends highly on the source of energy used. In this review, we present the current status of commercial DAC technologies and elucidate the five pillars of technology including capture technologies, their energy demand, final costs, environmental impacts, and political support. We explain processing steps for liquid and solid carbon capture technologies and indicate their specific energy requirements. DAC capital and operational cost based on plant power energy sources, land and water needs of DAC are discussed in detail. At 0.01 Mt CO/year capture capacity, DAC alone faces a challenge to meet the rates of carbon capture described in the goals of the Paris Agreement with 1.5-2°C of global warming. However, DAC may partially help to offset difficult to avoid annual emissions from concrete (∼8%), transportation (∼24%), iron-steel industry (∼11%), and wildfires (∼0.8%).
气候变化要求对负排放技术进行调整,例如直接空气捕获二氧化碳(CO₂),以降低温室气体对全球变暖的影响。最近,全球对直接空气捕获技术的兴趣高涨,促使全球实施新的税收抵免和新政策,这激励了现有的直接空气捕获公司,并引发了创业热潮。目前全球有19个直接空气捕获工厂在运营,每年捕获超过0.01 Mt CO₂。平均每年捕获10000吨CO₂的直接空气捕获活性工厂仍处于起步阶段,且成本高昂。直接空气捕获技术仍需在三个方面进行改进:1)接触器,2)吸附剂,3)再生,以降低成本。要实现每吨CO₂成本低于100美元,使直接空气捕获在经济上可行,就需要在这三个领域基于技术进行经济发展。目前直接空气捕获的成本比预期成本高约2至6倍,且高度依赖所使用的能源来源。在本综述中,我们介绍了商业直接空气捕获技术的现状,并阐明了该技术的五个支柱,包括捕获技术、能源需求、最终成本、环境影响和政治支持。我们解释了液体和固体碳捕获技术的处理步骤,并指出了它们的特定能源需求。详细讨论了基于工厂动力能源的直接空气捕获资本和运营成本、直接空气捕获所需的土地和水。以每年捕获0.01 Mt CO₂的能力计算,仅靠直接空气捕获要达到《巴黎协定》目标中描述的全球变暖1.5 - 2°C的碳捕获率面临挑战。然而,直接空气捕获可能有助于部分抵消混凝土(约8%)、交通运输(约24%)、钢铁行业(约11%)和野火(约0.8%)难以避免的年度排放量。