Energy Systems and Infrastructure Analysis Division, Argonne National Laboratory, 9700 South Cass Avenue, Lemont, Illinois 60439, United States.
Environ Sci Technol. 2022 Jun 21;56(12):7512-7521. doi: 10.1021/acs.est.2c00289. Epub 2022 May 16.
This study presents a life-cycle analysis of greenhouse gas (GHG) emissions of biodiesel (fatty acid methyl ester) and renewable diesel (RD, or hydroprocessed easters and fatty acids) production from oilseed crops, distillers corn oil, used cooking oil, and tallow. Updated data for biofuel production and waste fat rendering were collected through industry surveys. Life-cycle GHG emissions reductions for producing biodiesel and RD from soybean, canola, and carinata oils range from 40% to 69% after considering land-use change estimations, compared with petroleum diesel. Converting tallow, used cooking oil, and distillers corn oil to biodiesel and RD could achieve higher GHG reductions of 79% to 86% lower than petroleum diesel. The biodiesel route has lower GHG emissions for oilseed-based pathways than the RD route because transesterification is less energy-intensive than hydro-processing. In contrast, processing feedstocks with high free fatty acid such as tallow via the biodiesel route results in slightly higher GHG emissions than the RD route, mainly due to higher energy use for pretreatment. Besides land-use change and allocation methods, key factors driving biodiesel and RD life-cycle GHG emissions include fertilizer use and nitrous oxide emissions for crop farming, energy use for grease rendering, and energy and chemicals input for biofuel conversion.
本研究对生物柴油(脂肪酸甲酯)和可再生柴油(RD,即氢化油脂和脂肪酸)从油籽作物、玉米酒糟油、废食用油和牛脂生产的生命周期温室气体(GHG)排放进行了分析。通过行业调查收集了生物燃料生产和废脂肪加工的更新数据。与石油柴油相比,在考虑土地利用变化估算后,从大豆、油菜籽和麻疯树油生产生物柴油和 RD 的生命周期 GHG 排放量减少了 40%至 69%。将牛脂、废食用油和玉米酒糟油转化为生物柴油和 RD 可实现比石油柴油低 79%至 86%的更高 GHG 减排。与 RD 路线相比,基于油籽的生物柴油路线的 GHG 排放量较低,因为酯交换比氢化处理的能耗更低。相比之下,通过生物柴油路线处理高游离脂肪酸(如牛脂)的原料会导致 GHG 排放量略高于 RD 路线,主要是由于预处理的能源使用量更高。除了土地利用变化和分配方法外,生物柴油和 RD 生命周期 GHG 排放的驱动因素还包括作物种植的肥料使用和一氧化二氮排放、油脂加工的能源使用以及生物燃料转化的能源和化学品投入。