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全氟化合物在空气中的来源及传输途径综述

Review of Source and Transportation Pathways of Perfluorinated Compounds Through the Air.

作者信息

Owens Clyde V

机构信息

Air and Energy Management Division, Office of Research and Development, U.S. Environmental Protection Agency.

出版信息

J Environ Health. 2021 Jan-Feb;83(6):20-27.

Abstract

This article will identify the state of science on the generation, production, and transport of perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA). Additionally, this article will focus on the transport of these environmental contaminants through air sources. It is important to explore why air exposure is critical to bring awareness to a problem that is not always immediately apparent. From a biological standpoint, clean air is necessary to sustain healthy life. Thus, it is key to understand the environmental transport of chemicals such as PFOS and PFOA with regard to their ability to migrate (i.e., air to water and water to air) and thus create unsafe air. The fluorinated backbone of these substances is both hydrophobic and oleophobic/lipophobic, while the terminal functional group is hydrophilic (water loving). Therefore, PFOS and PFOA compounds tend to partition to interfaces, such as between air and water with the fluorinated backbone residing in air and the terminal functional group residing in water. This article will identify opportunities for research to further the understanding of their potential impacts to human health.

摘要

本文将阐述全氟辛烷磺酸(PFOS)和全氟辛酸(PFOA)的生成、产生及传输方面的科学现状。此外,本文将聚焦于这些环境污染物通过空气源的传输。探究空气暴露为何对于引起人们对一个并非总是立竿见影的问题的关注至关重要。从生物学角度来看,清洁空气是维持健康生活所必需的。因此,了解诸如PFOS和PFOA等化学物质在环境中的传输情况,尤其是它们的迁移能力(即从空气到水以及从水到空气)从而导致不安全空气的产生,这一点至关重要。这些物质的氟化主链既疏水又疏油/脂,而末端官能团是亲水的(爱水)。因此,PFOS和PFOA化合物倾向于分配到界面处,例如空气和水之间,氟化主链存在于空气中,末端官能团存在于水中。本文将确定进一步了解它们对人类健康潜在影响的研究机会。

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本文引用的文献

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Polyfluorinated compounds: past, present, and future.多氟化合物:过去、现在和未来。
Environ Sci Technol. 2011 Oct 1;45(19):7954-61. doi: 10.1021/es2011622. Epub 2011 Sep 9.

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