Kuai Chang-Sheng, A Ru-Han, Bao Zhi-Peng, Wu Xiao-Feng
Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
University of Chinese Academy of Sciences, Beijing 100049, China.
Org Lett. 2025 Sep 5;27(35):9807-9813. doi: 10.1021/acs.orglett.5c03213. Epub 2025 Aug 20.
A palladium-catalyzed difunctional fluoroalkylative carbonylation of 1,3-enynes with fluoroalkyl halides and ammonium iodide has been developed, providing rapid access to fluoroalkylated allenyl primary amides with a broad substrate scope, high chemo- and regioselectivity, and good functional group tolerance.
已开发出一种钯催化的1,3-烯炔与氟代烷基卤化物和碘化铵的双官能团氟烷基化羰基化反应，可快速获得具有广泛底物范围、高化学和区域选择性以及良好官能团耐受性的氟烷基化烯丙基伯酰胺。
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