Schmidt E W, Harper M K, Faulkner D J
Scripps Institution of Oceanography, University of California at San Diego, La Jolla 92093-0212, USA.
J Nat Prod. 1995 Dec;58(12):1861-7. doi: 10.1021/np50126a008.
Seven new pyrroloiminoquinone alkaloids, makaluvamines H-M [19-24] and damirone C[25], together with the known compounds, makaluvamines C[13], D[14], and G[17], were isolated from the sponge Zyzzya fuliginosa collected at Nahpali Island, Pohnpei, Micronesia. The structures of the new compounds were elucidated by interpretation of spectral data. The chemotaxonomic relationships involving the makaluvamines and related pyrroloiminoquinone alkaloids are discussed.
从密克罗尼西亚波纳佩州纳普利岛采集的海绵类动物黑海绵(Zyzzya fuliginosa)中,分离出了7种新的吡咯并亚氨基醌生物碱,即马卡鲁胺H-M [19 - 24]和达米罗酮C [25],以及已知化合物马卡鲁胺C [13]、D [14]和G [17]。通过光谱数据解析阐明了新化合物的结构,并讨论了马卡鲁胺及相关吡咯并亚氨基醌生物碱的化学分类关系。