The purpose of this study was to examine the relationships of achievement goal orientations and perceived motivational climate to perceptions of the intensity and direction of competitive state anxiety in a sample of university athletes representing various team sports. Although some studies have demonstrated that task orientation and mastery climate are associated with adaptive emotional patterns and ego orientation and performance climate are linked to less adaptive emotions, others have not verified these findings. In the present study, structural equation modeling was used to test these links. The results showed that perceptions of a performance climate were associated with ego orientation, whereas perceptions of a mastery climate were linked to task orientation. Furthermore, no significant links were found between task orientation and direction of competitive anxiety, while it was shown that the impact of ego orientation on the intensity and direction of cognitive and somatic anxiety was exerted through self-confidence. No significant direct links were found between motivational climates and competitive anxiety, thus implying that motivational climates may have an indirect impact on affective responses through the different goal orientations. The findings of the present study are discussed along with suggestions for examining situational and individual difference variables that may explain the relationships between intensity and direction of competitive anxiety and achievement goals and motivational climates.