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Transformation of an irregularly bridged epidithiodiketopiperazine to trichodermamide A.

作者信息

Seephonkai Prapairat, Kongsaeree Palangpon, Prabpai Samran, Isaka Masahiko, Thebtaranonth Yodhathai

机构信息

Department of Chemistry, Faculty of Science, Mahidol University, Bangkok, Thailand.

出版信息

Org Lett. 2006 Jul 6;8(14):3073-5. doi: 10.1021/ol061046l.

Abstract

[reaction: see text] An unusually bridged epidithiodiketopiperazine, pretrichodermamide A (3), was isolated from the fungus Trichoderma sp. BCC 5926. During the extensive effort to crystallize 3 for X-ray crystallographic analysis, conversion of this compound to trichodermamide A with coproduction of S(8) occurred.

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